[1]胡素贞,肖子敬.二维铜配合物聚合物[Cu(MDNS)2]n的合成与表征[J].华侨大学学报(自然科学版),2013,34(4):404-408.[doi:10.11830/ISSN.1000-5013.2013.04.0404]
 HU Su-zhen,XIAO Zi-jing.Synthesis and Characterization of 2D Coordination Polymer [Cu(MDNS)2]n[J].Journal of Huaqiao University(Natural Science),2013,34(4):404-408.[doi:10.11830/ISSN.1000-5013.2013.04.0404]
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二维铜配合物聚合物[Cu(MDNS)2n的合成与表征()
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《华侨大学学报(自然科学版)》[ISSN:1000-5013/CN:35-1079/N]

卷:
第34卷
期数:
2013年第4期
页码:
404-408
栏目:
出版日期:
2013-07-20

文章信息/Info

Title:
Synthesis and Characterization of 2D Coordination Polymer [Cu(MDNS)2n
文章编号:
1000-5013(2013)04-0404-05
作者:
胡素贞 肖子敬
华侨大学 材料科学与工程学院, 福建 厦门 361021
Author(s):
HU Su-zhen XIAO Zi-jing
College of Material Science and Engineering, Huaqiao University, Xiamen 361021, China
关键词:
35-二硝基水杨酸甲酯 Cu(Ⅱ) 配位聚合物 晶体结构 溶液法
Keywords:
methyl 35-dinitrosalicylate Cu(Ⅱ) coordination polymer crystal structure property
分类号:
O641.4
DOI:
10.11830/ISSN.1000-5013.2013.04.0404
文献标志码:
A
摘要:
采用溶液法合成铜的配位聚合物[Cu(MDNS)2n(HDNS=3,5-二硝基水杨酸甲酯).研究表明,该化合物属单斜晶系,空间群为P21/c,分子式为C8H6N2O7.其晶胞参数:a=1.100 2(4)nm, b=1.123 3(4)nm,c=0.814 6(3)nm, β=107.970(6)°, V=0.957 7(6)nm3, Z=2,μ=1.233 mm-1, Dc=1.893 g·cm-3, F(000)=555, R=0.034 6,Rw=0.102 6.在标题化合物中,Cu2+离子由2个3,5-二硝基水杨酸甲酯的2个羰基氧原子和2个酚氧原子,以及另2个3,5-二硝基水杨酸甲酯的2个硝基氧原子配位,共同形成CuO6畸变的八面体配位构型.每一个3,5-二硝基水杨酸甲酯都同时桥联2个Cu2+离子,将化合物联结成二维网状结构的配位聚合物.
Abstract:
A new 2D coordination polymer of [Cu(MDNS)2n(HDNS=methyl 3,5-dinitrosalicylate, C8H6N2O7)has been prepared and structurally characterized. It crystallizes in triclinic system, space group P21/c with a=1.100 2(4)nm, b=1.123 3(4)nm, c=0.814 6(3)nm, β=107.970(6)°, V=0.957 7(6)nm3, Z=2, μ=1.233 mm-1, Dc=1.893 g·cm-3, F(000)=555, R=0.034 6, Rw=0.102 6. Cu(Ⅱ)atom in the title compound has a distorted CuO6 octahedral coordination. Four donors(two carbonyl oxygen, two phenol oxygen)of two methyl 3,5-dinitrosalicylate ligands comprise the basal plane. Two nitro oxygen atoms from the other two methyl 3,5-dinitrosalicylate ligands occupy axial positions. Every two Cu(Ⅱ)atoms are bridged by one methyl 3,5-dinitrosalicylate ligand to generate two-dimensional Cu(Ⅱ)coordination polymer.

参考文献/References:

[1] LAMA P,SA(~overN)UDO E C,BHARADWAJ P K.Coordination polymers of Mn2+ and Dy3+ ions built with a bent tricarboxylate: Metamagnetic and weak anti-ferromagnetic behavior[J].Dalton Trans,2012,41(10):2979-2985.
[2] YANG Peng,HE Xiang,LI Ming-xing,et al.The first homochiral coordination polymer with temperature-independent piezoelectric and dielectric properties[J].J Mater Chem,2012,22(6):2398-2400.
[3] HASHEMI L,MORSALI A.Microwave assisted synthesis of a new lead(Ⅱ)porous three-dimensional coordination polymer: Study of nanostructured size effect on high iodide adsorption affinity[J].Cryst Eng Comm,2012,14(3):779-781.
[4] WANG Kuai-bing, YIN Yu-xin, WANG Zhi-lin, et al. Facile synthesis of zinc(Ⅱ)-carboxylate coordination polymer particles and their luminescent, biocompatible and antibacterial properties[J]. Cryst Eng Comm,2011,13(20):6231-6236.
[5] ZHANG Jian-yong,JING Xue-hui,MA Yu,et al.Interpenetration,self-catenation, and new topology in metal-organic frameworks of cobalt with mixed organic linkers[J].Cryst Growth Des,2011,11(9):3681-3685.
[6] YANG En-cui,LIU Zhong-yi,ZHAO Xiao-jun,et al.Ligand-deprotonation induced structural diversity in a ternary Cu-triazoletetracarboxylate self-assembly system: Synthesis,crystal structures, and magnetic behavior[J].Cryt Eng Comm,2011,13(17):5401-5408.
[7] WANG Feng-qin,LU Fan-li,WEI Bin,et al.Poly[[di-μ-aqua-tetraaquadi-μ-hydroxide-bis(μ3-3-nitrophthalato)-tricopper(Ⅱ)] dihydrate][J].Acta Cryst,2009,C65(1):m42-m44.
[8] LIU Zhong-yi,CHU Jing,DING Bo,et al.A novel Cu5 cluster-based 3D magnetic framework with an overall S=
  1/2 spin ground state[J].Inorg Chem Commun,2011,14(6):925-928.
[9] MENG Yan.Poly[(l-2-hydroxy-3,5-dinitrobenzoato)-rubidium][J].Acta Cryst,2011,E67(4):454.
[10] HU Man-cheng, GENG Chun-yu, LI Shu-ni, et al.Syntheses and crystal structures of three cesium salts: Cesium 5-sulfosalicylate, cesium 3,5-dinitrosalicylate and cesium 2,4-dinitrophenoxide monohydrate[J].J Organomet Chem,2005,690(13):3118-3124.
[11] SONG Wen-dong,GUO Xian-xia,ZHANG Chao-hua.Poly[aqua(μ3-3,5-dinitrosalicylato)calcium(Ⅱ)][J].Acta Cryst,2007,E63(2):m399-m401.
[12] SONG Wen-dong, FAN Run-zhen, GU Chang-sheng, et al. Poly[[μ2-aqua-aqua(μ3-3,5-dinitro-salicylato)barium(Ⅱ)] monohydrate][J].Acta Cryst,2008,E64(4):m551.
[13] MA Shu-lin,REN Shi,YANG Yun.New binuclear complexes with mixed ligands and μ2-phenol oxygen bridges:Synthesis crystal structures and magnetism[J].J Inorg Organomet Polym,2010,20(1):104-109.
[14] ERXLEGEN A.Copper coordination to the aldehyde and hemiacetal form of 4-bromo-2-[(2-diethylaminoethyl)ethylaminomethyl]-6-formylphenol[J].Inorg Chim Acta,2009,362(3):839-844.
[15] CHEN Li-hua,ZHAO Gan-qing,WANG Xiang.(2-acetylphenolato)(2,2-bipyridine)-nitrato copper(Ⅱ)[J].Acta Cryst,2009,E65(11):m1427.
[16] GERAGHTY M,SHERIDAN V,MCCANN M.Synthesis and anti-candida activity of copper(Ⅱ)and manganese(Ⅱ)carboxylate complexes[J].Polyhedron,1999,18(22):2931-2939.
[17] QU Yang,PENG Jian-jun.Tetraamminebis(4-nitrobenzoato-κO)copper(Ⅱ)[J].Acta Cryst,2006,E62(5):m952-m953.
[18] LIU Zhi-qiang,LI Yan-tuan,WU Zhi-yong,et al.A two-dimensional copper(Ⅱ)polymer with bridging μ-trans-oxamidate and μ2-picrate ligands: Synthesis, crystal structure and DNA binding studies[J].Inorg Chim Acta,2008,361(1):226-232.

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备注/Memo

备注/Memo:
收稿日期: 2012-12-04
通信作者: 肖子敬(1962-),男,教授,主要从事配位化学方向的研究.E-mail:zijxiao@163.com.
基金项目: 国家自然科学基金资助项目(50971063); 福建省自然科学基金资助项目(E0640006, 2010J01042)
更新日期/Last Update: 2013-07-20