[1]林碧洲.某些有机铵十聚钨酸盐的制备和催化性质[J].华侨大学学报(自然科学版),2002,23(3):300-303.[doi:10.3969/j.issn.1000-5013.2002.03.017]
　Lin Bizhou.Preparation and Catalytic Properties of Some Organoammonium Decatungstates[J].Journal of Huaqiao University(Natural Science),2002,23(3):300-303.[doi:10.3969/j.issn.1000-5013.2002.03.017]
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某些有机铵十聚钨酸盐的制备和催化性质()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第23卷
期数:
2002年第3期
页码:
300-303
栏目:
出版日期:
2002-07-20

文章信息/Info

Title:
Preparation and Catalytic Properties of Some Organoammonium Decatungstates
文章编号:
1000-5013(2002)03-0300-04
作者:
林碧洲
华侨大学材料科学与工程学院 泉州362011
Author(s):
Lin Bizhou
College of Mater. Sci. & Eng., Huaqiao Univ., 362011, Quanzhou
关键词:
十聚钨酸盐;  烷烃催化氧化;  光催化
Keywords:
decatungstates;  catalytic oxidation of alkanes;  photocatalysis
分类号:
O621.25
DOI:
10.3969/j.issn.1000-5013.2002.03.017
文献标志码:
A
摘要:
制备四乙基铵、二异丙铵和六氢吡啶十聚钨酸盐,通过元素分析、红外吸收光谱和热分析,对这 3种有机铵十聚钨盐进行表征 .在 3种有机铵十聚钨酸盐的环已烷光催化氧化反应中,环已醇和环已酮为主要产物,其中 [(C2 H5) 4 N]4W10 O3 2 和 [(C5H10 NH2 ]4W10 O3 2 对环已酮的选择性优于环已醇,而 { [(CH3 ) 2 CH]2 NH2 } 4 W10 O3 2 对环己醇的选择性则优于环己酮 .
Abstract:
Some organoammonium decatungstates may serve as photocatalysts for the oxidation of alkanes. Among them, tetraethylammonium, diisopropylammonium and piperidine decatungstates are prepared; and they are characterized by element analyse, infrared spectra and thermal analyse. The oxidation reaction of cyclohexane under their photocatalysis give rise to cyclohexanol and cyclohexanone as main products. The former two decatungstates present a good selectivity for the cyclohexanone formation, with the latter one shows a good selectivity for the cyclohexanol formation.

参考文献/References:

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备注/Memo

备注/Memo:
福建省自然科学基金资助项目
更新日期/Last Update: 2014-03-23