[1]张艺,李华杰,张建平,等.水合肼修饰壳聚糖在卷烟烟气吸附的应用[J].华侨大学学报(自然科学版),2020,41(5):625-630.[doi:10.11830/ISSN.1000-5013.202005024]
　ZHANG Yi,LI Huajie,ZHANG Jianping,et al.Application of Hydrazine Hydrate Modified Chitosan onAdsorption of Cigarette Smoke[J].Journal of Huaqiao University(Natural Science),2020,41(5):625-630.[doi:10.11830/ISSN.1000-5013.202005024]
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水合肼修饰壳聚糖在卷烟烟气吸附的应用()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第41卷
期数:
2020年第5期
页码:
625-630
栏目:
出版日期:
2020-09-20

文章信息/Info

Title:
Application of Hydrazine Hydrate Modified Chitosan onAdsorption of Cigarette Smoke
文章编号:
1000-5013(2020)05-0625-06
作者:
张艺1;  李华杰2;  张建平2;  李明春1;  辛梅华1
1. 华侨大学 材料科学与工程学院, 福建 厦门 361021;2. 福建中烟工业有限责任公司 技术中心, 福建 厦门 361012
Author(s):
ZHANG Yi1;  LI Huajie2;  ZHANG Jianping2;  LI Mingchun1;  XIN Meihua1
1. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China; 2. Technology Center, China Tobacco Fujian Industrial Limited Company, Xiamen 361012, China
关键词:
壳聚糖;  水合肼;  卷烟主流烟气;  有害成分;  吸附
Keywords:
chitosan;  hydrazine hydrate;  mainstream cigarette smoke;  harmful components;  adsorption
分类号:
TS411.2
DOI:
10.11830/ISSN.1000-5013.202005024
文献标志码:
A
摘要:
以壳聚糖(CS)、水合肼等为原料,制备氨基化壳聚糖(AHCS).采用傅里叶红外光谱、X-射线衍射及热重分别对产物的化学结构、结晶性和热稳定性进行表征.将CS和AHCS作为添加剂分别添加到卷烟滤嘴中,研究其对卷烟主流烟气中有害成分的吸附作用.对卷烟烟气中有害成分及气粒相物进行测定,结果表明:含CS和AHCS的卷烟滤嘴的危害指数分别为7.41和7.11,与常规滤嘴相比分别下降7.84%和11.57%;添加AHCS滤嘴的苯酚释放量为6.92 μg·支-1,下降30.52%,其对苯酚具有选择性吸附.
Abstract:
Aminatied chitosan(AHCS)was prepared from chitosan(CS)and hydrazine hydrate. The chemical structure, crystallinity, and thermal stability of AHCS were characterized by Fourier transform infrared, X-ray diffraction, and thermogravimetric analysis, respectively. CS and AHCS were added into cigarette filters to probe their adsorption capability for the harmful components in the cigarette smoke, and the harmful components and gaseous particles in cigarette smoke were determined. The results show that: the harm indexes of cigarette filter containing CS and AHCS are 7.41 and 7.11, which are 7.84% and 11.57% lower than that of conventional filter, respectively. Particularly, the filter with AHCS demonstrates selective adsorption for phenol in the cigarette smoke, which has release amount of 6.92 μg per branch for phenol, 30.52% lower than that of conventional filter.

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备注/Memo

备注/Memo:
收稿日期: 2020-05-22
通信作者: 辛梅华(1962-),女,教授,博士,博士生导师,主要从事功能高分子材料的研究.E-mail:mhxin@hqu.edu.cn.
基金项目: 福建省海洋高新产业发展专项(闽海洋高新［2015］22号); 福建省高校产学合作项目(2019H6014)
更新日期/Last Update: 2020-09-20