[1]刘勇军,邹瑜.渣油加氢脱金属催化剂的积炭分析[J].华侨大学学报(自然科学版),2014,35(2):180-184.[doi:10.11830/ISSN.1000-5013.2014.02.0180]
　LIU Yong-jun,ZOU Yu.Analysis of the Coking of Residue Hydrodemetallization Catalyst[J].Journal of Huaqiao University(Natural Science),2014,35(2):180-184.[doi:10.11830/ISSN.1000-5013.2014.02.0180]
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渣油加氢脱金属催化剂的积炭分析()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第35卷
期数:
2014年第2期
页码:
180-184
栏目:
出版日期:
2014-03-20

文章信息/Info

Title:
Analysis of the Coking of Residue Hydrodemetallization Catalyst
文章编号:
1000-5013(2014)02-0180-05
作者:
刘勇军;  邹瑜
华侨大学 化工学院, 福建 厦门 361021
Author(s):
LIU Yong-jun;  ZOU Yu
College of Chemical Engineering, Huaqiao University, Xiamen 361021, China
关键词:
渣油;  加氢脱金属;  催化剂;  积炭
Keywords:
residue;  hydrodemetallization;  catalyst;  coke deposition
分类号:
TE625.25
DOI:
10.11830/ISSN.1000-5013.2014.02.0180
文献标志码:
A
摘要:
采用傅里叶红外光谱(FT-IR)、热重(TGA)和固体核磁(13C NMR)等方法,研究渣油加氢脱金属过程中积炭在催化剂上的沉积类型、沉积过程及其结构演变.结果表明:催化剂表面上的积炭可明显地分辩为两种不同类型的炭,即致密炭和疏松炭.在整个渣油加氢脱金属过程中,随着反应的进行,积炭结构逐步由富脂肪型炭向芳香型炭转变,积炭的前后沉积模式存在明显的“先快后慢”特征.
Abstract:
The structural evolution, deposition type and pattern of coke on residue hydrodemetallization catalyst were studied by FT-IR, TGA and 13C NMR. The results showed that two types of cokes on the surface of catalysts were observed definitely: refractory coke and soft coke. The comparative study of fresh and used catalysts showed that the aliphatic structures of coke are gradually translated into aromatic structures with increasing catalyst age. The coke deposition, during entire hydroprocessing period, is characterized by “growing fast at the beginning and then getting slow”.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期: 2013-04-28
通信作者: 刘勇军(1981-),男,讲师,主要从事能源化工与催化的研究.E-mail:yongjunliu@hqu.edu.cn.
基金项目: 福建省教育厅A类科技项目(JA12008)
更新日期/Last Update: 2014-03-20