[1]刘小英,郑燕玉.腰果酚醛胺聚合物的制备及其性能测试[J].华侨大学学报(自然科学版),2013,34(1):63-67.[doi:10.11830/ISSN.1000-5013.2013.01.0063]
　LIU Xiao-ying,ZHENG Yan-yu.Preparation and Performance Test of Cardanol Aldehyde-Amine Polymers[J].Journal of Huaqiao University(Natural Science),2013,34(1):63-67.[doi:10.11830/ISSN.1000-5013.2013.01.0063]
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腰果酚醛胺聚合物的制备及其性能测试()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第34卷
期数:
2013年第1期
页码:
63-67
栏目:
出版日期:
2013-01-20

文章信息/Info

Title:
Preparation and Performance Test of Cardanol Aldehyde-Amine Polymers
文章编号:
1000-5013(2013)01-0063-05
作者:
刘小英;  郑燕玉
泉州师范学院 化学与生命科学学院, 福建 泉州 362000
Author(s):
LIU Xiao-ying;  ZHENG Yan-yu
College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou 362000, China
关键词:
腰果酚;  胺;  腰果酚醛胺聚合物;  缩聚反应;  甲醛
Keywords:
cardanol;  amine;  cardanol aldehyde-amine polymer;  poly-condensation;  formaldehyde
分类号:
O636
DOI:
10.11830/ISSN.1000-5013.2013.01.0063
文献标志码:
A
摘要:
采用溶液缩聚法,以碱为催化剂,由腰果酚、甲醛分别与乙二胺、二乙撑三胺、已二胺制备腰果酚醛胺聚合物,并通过元素分析(EA)、红外光谱分析(FT-IR)、凝胶渗透色谱(GPC)和热分析系统(DSC-TG)等对所制备的聚合物进行结构表征与性能测试.结果表明:该缩聚物分子结构中含有-OH,-NH-,-NH2等功能基;同时,腰果酚醛胺聚合物具有优良的固化成膜性、物理机械性能、耐化学介质性能和热稳定性,以及能与环氧树脂进行固化交联和吸附重金属离子的性能.
Abstract:
Cardanol aldehyde-amine polymers were prepared by solution poly-condensation of cardanol,formaldehyde and 1,2-ethanediamine, diethylenetriamine, 1,6-hexanediamine using base as catalyst. The structures of the prepared polymers were characterized by EA, FT-IR, GPC and DSC-TG, and the performances of these polymers were also investigated. The results indicated that the condensation polymers had functional groups such as -OH,-NH- and -NH2 in their structures. Furthermore, the cardanol aldehyde-amine polymers had excellent film forming ability, physico-mechanical properties, resistance against chemical media and thermo-stability. The polymers could also cure with epoxy resin(ER)and adsorb heavy metal ions.

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备注/Memo

备注/Memo:
收稿日期: 2012-09-02
通信作者: 郑燕玉(1966-),女,教授,主要从事天然高分子的研究.E-mail:yy410529@163.com.
基金项目: 福建省教育厅科研基金资助项目(JA11222); 福建省泉州市科技计划资助项目(2011Z21)
更新日期/Last Update: 2013-01-20