[1]胡文英,孙向英,何燕芳.铜铁氰自组装多层膜修饰电极的制备及性能[J].华侨大学学报(自然科学版),2008,29(1):30-33.[doi:10.11830/ISSN.1000-5013.2008.01.0030]
　HU Wen-ying,SUN Xiang-ying,HE Yan-fang.Preparation and Characterizations of Copper Hexacyanoferrate Self-Assembled Multilayer Films Modified Electrode[J].Journal of Huaqiao University(Natural Science),2008,29(1):30-33.[doi:10.11830/ISSN.1000-5013.2008.01.0030]
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铜铁氰自组装多层膜修饰电极的制备及性能()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第29卷
期数:
2008年第1期
页码:
30-33
栏目:
出版日期:
2008-01-20

文章信息/Info

Title:
Preparation and Characterizations of Copper Hexacyanoferrate Self-Assembled Multilayer Films Modified Electrode
文章编号:
1000-5013(2008)01-0030-04
作者:
胡文英; 孙向英; 何燕芳
华侨大学材料科学与工程学院; 华侨大学材料科学与工程学院 福建泉州362021; 福建泉州362021
Author(s):
HU Wen-ying;  SUN Xiang-ying;  HE Yan-fang
College of Material Science and Engineering, Huaqiao University, Quanzhou 362021, China
关键词:
铜铁氰化物;  自组装多层膜;  电化学分析;  对苯二酚
Keywords:
copper hexacyanoferrate;  self-assembled multilayer film;  electroanalysis;  hydroquinone
分类号:
O646
DOI:
10.11830/ISSN.1000-5013.2008.01.0030
文献标志码:
A
摘要:
利用层层组装技术,通过Cu2+的桥联作用,制备出铜铁氰自组装膜修饰电极(CuHCF/L-Cys/Au),并研究扫描速度、支持电解质、pH值对该修饰电极电化学性能的影响.结果表明,铜铁氰自组装膜修饰电极具有良好的稳定性和重现性,方法简单易行、干扰小,对对苯二酚具有较好的选择性,其催化电流与对苯二酚浓度在2.0×10-5~2.4×10-4mol.L-1范围呈良好的线性关系.
Abstract:
With layer-by-layer assembling technology,another kind of multilayer films CuHCF/L-Cys/Au modified electrode was prepared based on the bridge function of Cu(2+),the effects such as scan rate,electrolyte and pH on the electrochemical properties of the electrode were studied.The experimental results show that the method was simple,small disturbance and CuHCF/L-Cys/Au electrode had good stability and repeatability and high selectivity to hydroquinone.The catalysis currents have good linearity with hydroquinone concentration within the range of 2.0×10(-5)~2.4×10(-4) mol·L(-1).

参考文献/References:

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备注/Memo

备注/Memo:
国家自然科学基金资助项目(20575023); 福建省国际合作重点项目(2006I0021); 福建省自然科学基金资助项目(D0410019,D0710017); 国务院侨办基金资助项目(06QZR10)
更新日期/Last Update: 2014-03-23