[1]刘斌,张名楠,孙向英,等.三苯基锡印迹聚合物的合成及吸附性能[J].华侨大学学报(自然科学版),2005,26(1):47-50.[doi:10.3969/j.issn.1000-5013.2005.01.012]
　Liu Bin,Zhang Mingnan,Sun Xiangying,et al.Synthesis and Adsorbability of the Engram Polymer of Triphenyltin[J].Journal of Huaqiao University(Natural Science),2005,26(1):47-50.[doi:10.3969/j.issn.1000-5013.2005.01.012]
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三苯基锡印迹聚合物的合成及吸附性能()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第26卷
期数:
2005年第1期
页码:
47-50
栏目:
出版日期:
2005-01-20

文章信息/Info

Title:
Synthesis and Adsorbability of the Engram Polymer of Triphenyltin
文章编号:
1000-5013(2005)01-0047-04
作者:
刘斌; 张名楠; 孙向英; 徐金瑞
华侨大学材料科学与工程学院; 华侨大学材料科学与工程学院 福建泉州362021; 福建泉州362021; 福建泉州362021
Author(s):
Liu Bin;  Zhang Mingnan;  Sun Xiangying;  Xu Jinrui
College of Material Science and Engineering, Huaqiao University, 362021, Quanzhou, China
关键词:
三苯基锡;  分子印迹聚合物;  壳聚糖;  吸附性能
Keywords:
triphenyltin;  molecular engram polymer;  chitosan
分类号:
O634; O647.3
DOI:
10.3969/j.issn.1000-5013.2005.01.012
文献标志码:
A
摘要:
以壳聚糖为聚合物单体,以三苯基锡 (TPT)为模板分子,制备在空间结构和结合位点上与TPT完全匹配的TPT模板交联壳聚糖分子印迹聚合物 (TMIPCLC) .研究该分子印迹聚合物的吸附、交联和洗脱条件,以及对TPT的吸附能力 .结果表明,所合成TMIPCLC对TPT具有良好的吸附选择性 .
Abstract:
Taking chitosan as monomer of polymer and triphenyltin (TPT) as molecule of formwork, the authors prepare the molecular engram polymer of triphenyltin cross linking chitosan which completely matches with TPT in space structure and binding site. A further study is made on the condition of adsorption, cross linking and elution of this molecular engram polymer as well as its adsorbability on TPT. The results show that the molecular engram polymer so synthesized possesses good adsorptive selectivity on TPT.

参考文献/References:

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[2] Dimitriou P, Castritsi-Catharios J, Miliou H. Acute toxicity effects of tributylyin chloride and triphenyltin chloride on gilthead seabream, Sparus aurata L., embryos [J]. Ecotoxicology and Environmental Safety, 2003, (1):30-35.doi:10.1016/S0147-6513(02)00008-8.
[3] Whalen M M, Wilson S, Gleghorn C. Brief exposure to triphenyltin produces irreversible inhibition of the cytotoxic function of human natural killer cells [J]. Environmental Research, 2003, (3):213-220.doi:10.1016/S0013-9351(03)00043-4.
[4] 石孝洪, 魏世强, 李军. 有机锡化合物的环境化学行为及效应 [J]. 重庆大学学报(自然科学版), 2003(7):104-107.doi:10.3969/j.issn.1000-582X.2003.07.027.
[5] 秦晓光, 张经. 天然水体有机锡的富集分离方法 [J]. 海洋环境科学, 2001(3):60-66.doi:10.3969/j.issn.1007-6336.2001.03.014.
[6] 蒋挺大. 壳聚糖 [M]. 北京:中国环境科学出版社, 2001.179-20.
[7] Cormack P A G, Elorza A Z. Molecularly imprinted polymers:Synthesis and characterisation [J]. Journal of Chromatography B, 2004(1):173-182.doi:10.1016/j.jchromb.2004.02.013.

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备注/Memo

备注/Memo:
福建省自然科学基金资助项目(D0310016)
更新日期/Last Update: 2014-03-23