[1]王翰文,杨斌,苏江波,等.马来松香聚乙二醇酯表面活性剂的制备及性能分析[J].华侨大学学报(自然科学版),2024,45(5):596-602.[doi:10.11830/ISSN.1000-5013.202407011]
　WANG Hanwen,YANG Bin,SU Jiangbo,et al.Preparation and Performance Analysis of Malay Rosin Polyethylene Glycol Ester Surfactants[J].Journal of Huaqiao University(Natural Science),2024,45(5):596-602.[doi:10.11830/ISSN.1000-5013.202407011]
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马来松香聚乙二醇酯表面活性剂的制备及性能分析()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第45卷
期数:
2024年第5期
页码:
596-602
栏目:
出版日期:
2024-09-20

文章信息/Info

Title:
Preparation and Performance Analysis of Malay Rosin Polyethylene Glycol Ester Surfactants
文章编号:
1000-5013(2024)05-0596-07
作者:
王翰文1; 2; 3;  杨斌4;  苏江波4;  饶小平1; 2; 3
1. 华侨大学 化工学院, 福建 厦门 361021;2. 华侨大学 先进碳转化技术研究院, 福建 厦门 361021;3. 华侨大学 生物质低碳转化福建省高校重点实验室, 福建 厦门 361021;4. 福建南平青松化工有限公司 福建省松节油加工重点实验室, 福建 南平 354299
Author(s):
WANG Hanwen1; 2; 3;  YANG Bin4;  SU Jiangbo4;  RAO Xiaoping1; 2; 3
1. College of Chemical Engineering, Huaqiao University, Xiamen 361021, China; 2. Academy of Advanced Carbon Conversion Technology, Huaqiao University, Xiamen 361021, China; 3. Fujian Provincial Key Laboratory of Biomass Low-Carbon Conversion, Huaqiao University, Xiamen 361021, China; 4. Fujian Provincial Turpentine Processing Key Laboratory, Fujian Nanping Qingsong Chemical Company Limited, Nanping 354299, China
关键词:
马来松香聚乙二醇酯表面活性剂;  Diels-Alder加成反应;  松香;  马来松香;  聚乙二醇
Keywords:
Malay rosin polyethylene glycol ester surfactant(SM600);  Diels-Alder addition reaction;  rosin;  maleic rosin;  polyethylene glycol
分类号:
TQ423
DOI:
10.11830/ISSN.1000-5013.202407011
文献标志码:
A
摘要:
为了解决农用乳化剂对石油依存度大、环境友好性差等问题,以可再生资源松香为原料,经异构化及Diels-Alder加成反应合成了马来松香,然后与聚乙二醇600反应,合成马来松香聚乙二醇酯表面活性剂(SM600);用傅里叶红外光谱仪(FT-IR)和凝胶色谱仪(GPC)对产物的结构进行表征,并对其外观颜色、酸值、水溶液的pH值、粘度、浊点、聚合度(DP)进行检测,以及对表面张力(γ)、临界胶束质量分数(wCMC)、泡沫性能(FP)、乳化性能(EP)和亲水亲油平衡值(HLB)等表面活性性能进行研究。结果表明:SM600在室温下呈棕红色液体单相透明,具有酸值低、粘度低及浊点高等特点,其水溶液呈中性,聚合度为1.81,表面张力和临界胶束质量分数分别为36.139 mN·m-1和0.063%,表现出良好的泡沫性能、乳化性能和亲水性。原料天然可再生,合成工艺简单,产品性能良好,可用于替代烷基酚聚氧乙烯醚乳化剂。
Abstract:
In order to solve the problems of high dependence on petroleum and poor environmental friendliness of agricultural emulsifiers, rosin, a renewable resource, was utilized as the raw material to synthesize maleic rosin through isomerization and Diels-Alder addition reactions. Subsequently, maleic rosin was reacted with polyethylene glycol 600 to synthesize a malay rosin polyethylene glycol ester surfactant(SM600). The structural characterization of the product was performed using Fourier-transform infrared spectroscopy(FT-IR)and gel permeation chromatography(GPC). Additionally, the appearance color, acid value, pH value of the aque-ous solution, viscosity, cloud point and degree of polymerization(DP)were measured. Furthermore, surface tension(γ), critical micelle mass fraction(wCMC), foam performance(FP), emulsification performance(EP), and hydrophilic-lipophilic balance(HLB)were studied to evaluate the surface activity performance. The results indicate that SM600 appears as a reddish-brown liquid at room temperature, exhibiting characteristics such as low acid value, low viscosity and high cloud point. Its aqueous solution is neutral with a polymerization degree of 1.81. The surface tension and critical micelle mass fraction are 36.139 mN·m-1 and 0.063%, respectively, demonstrating excellent foam performance, emulsification performance and hydrophilicity. The raw materials are naturally renewable, the synthesis process is simple, and the product exhibits excellent performance, making it a potential substitute for alkylphenol polyoxyethylene ether emulsifiers.

参考文献/References:

[1] 崔正刚.表面活性剂、胶体与界面化学基础[M].北京:化学工业出版社,2013.
[2] 裴鸿,张利国.2017年中国表面活性剂原料及产品产销统计分析[J].日用化学品科学,2018,41(4):1-6.DOI:10.13222/j.cnki.dc.2018.04.001.
[3] 黄旭娟,刘鹤,王磊,等.聚合植物油脂表面活性剂的制备及其结构与性能[J].化工进展,2016, 35( 2):575-580.DOI:10.16085/j.issn.1000-6613.2016.02.037.
[4] FAN Yaxun,WANG Yilin.Deposition and spread of aqueous pesticide droplets on hydrophobic/superhydrophobic surfaces by fast aggregation of surfactants[J].Langmuir: The ACS Journal of Surfaces and Colloids,2023,39(16):5631-5640.DOI:10.1021/acs.langmuir.3c00282.
[5] BAO Zhenping,WU Yanling,SONG Ridan,et al.The simple strategy to improve pesticide bioavailability and minimize environmental risk by effective and ecofriendly surfactants[J].Science of The Total Environment,2022,851(Pt 1),158169.DOI:10.1016/j.scitotenv.2022.158169.
[6] 汪侠.表面活性剂研发现状及未来发展前景研究[J].化工设计通讯,2023,49(4):55-57.DOI:10.3969/j.issn.1003-6490.2023.04.020.
[7] JOHNSON P,TRYBALA A,STAROV V,et al.Effect of synthetic surfactants on the environment and the potential for substitution by biosurfactants[J].Adv Colloid Interface Sci,2021,288:102340.DOI:10.1016/j.cis.2020.102340.
[8] REBELLO S,ASOK A K,MUNDAYOOR S,et al.Surfactants: Toxicity,remediation and green surfactants[J].Environmental Chemistry Letters,2014,12(2):275-287.DOI:10.1007/s10311-014-0466-2.
[9] 王翔,代加林,杨梦.高分子表面活性剂的发展及应用现状[J].塑料工业,2007(增刊1):22-24,35.DOI:10.3321/j.issn:1005-5770.2007.z1.006.
[10] 唐胜男,张安琪.绿色表面活性剂分类综述[J].中国化妆品,2023(4):104-108.
[11] PRADHAN A,BHATTACHARYYA A.Quest for an eco-friendly alternative surfactant: Surface and foam characteristics of natural surfactants[J].Journal of Cleaner Production,2017,150:127-134.DOI:10.1016/j.jclepro.2017.03.013.
[12] 叶圣丰,翟兆兰,饶小平,等.松香基表面活性剂研究进展[J].生物质化学工程,2022,56(3):67-74.DOI: 10.3969/j.issn.1673-5854.2022.03.010.
[13] 宋湛谦.松香化学与应用[J].化工时刊,1990(7):11-18.
[14] 宋湛谦.松香的精细化工利用(Ⅰ): 松香的组成与性质[J].林产化工通讯,2002(4):29-33.DOI:10.3969/j.issn.1673-5854.2002.04.009.
[15] WANG Hanwen, ZHANG Hangyuan, WU Qian,et al.Pickering emulsions and viscoelastic solutions constructed by a rosin-based CO2-responsive surfactant[J].Langmuir: The ACS Journal of Surfaces and Colloids,2023,39(44),15653-15664.DOI:10.1021/acs.langmuir.3c02085.
[16] 周永红,宋湛谦.松香的精细化工利用(Ⅳ): 松香类表面活性剂的合成与应用[J].林产化工通讯,2003(1):28-32.DOI:10.3969/j.issn.1673-5854.2003.01.008.
[17] 任天瑞,李永红.松香化学及其应用[M].北京:化学工业出版社,2007.
[18] 郑建强, 刘莉, 饶小平,等.松香基胆碱季铵盐表面活性剂的合成及抑菌活性研究[J].林产化学与工业,2015,35(5):98-104.DOI:10.3969/j.issn.0253-2417.2015.05.016.
[19] YAN Xinyan,ZHAI Zhaolan,XU Ji,et al.CO2-responsive pickering emulsions stabilized by a bio-based rigid surfactant with nanosilica[J].J Agric Food Chem,2018,66(41),10769-10776.DOI:10.1021/acs.jafc.8b03458.
[20] 王丽艳,杨佳,李云晴,等.含多官能团Gemini表面活性剂的合成及性能[J].化工进展,2020,39(8):3278-3286.DOI:10.16085/j.issn.1000-6613.2019-1570.
[21] KAIZU K,ALEXANDRIDIS P.Effect of surfactant phase behavior on emulsification[J].J Colloid Interface Sci,2016,466:138-149.DOI:10.1016/j.jcis.2015.10.016.
[22] 王早骧.表面活性剂的亲水亲油平衡(HLB)及其在农药制剂研究中的应用[J].精细化工,1986(2):7-22.DOI:10.13550/j.jxhg.1986.02.002.

备注/Memo

备注/Memo:
收稿日期: 2024-07-11
通信作者: 饶小平(1978-),男,教授,博士,博士生导师,主要从事松香化学品高值化利用的研究。E-mail:raoxp@hqu.edu.cn。
基金项目: 福建省南平市科技计划项目(N2022B005)https://hdxb.hqu.edu.cn/
更新日期/Last Update: 2024-09-20