[1]陈晓缘,金春英,林金清.废水中离子液体高级氧化降解研究进展[J].华侨大学学报(自然科学版),2024,45(4):423-438.[doi:10.11830/ISSN.1000-5013.202407036]
　CHEN Xiaoyuan,JIN Chunying,LIN Jinqing.ResearchProgress on Degradation of Ionic Liquids in Wastewater Through Advanced Oxidative Processes[J].Journal of Huaqiao University(Natural Science),2024,45(4):423-438.[doi:10.11830/ISSN.1000-5013.202407036]
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废水中离子液体高级氧化降解研究进展()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第45卷
期数:
2024年第4期
页码:
423-438
栏目:
出版日期:
2024-07-20

文章信息/Info

Title:
ResearchProgress on Degradation of Ionic Liquids in Wastewater Through Advanced Oxidative Processes
文章编号:
1000-5013(2024)04-0423-16
作者:
陈晓缘1;  金春英2;  林金清1
1. 华侨大学 材料科学与工程学院, 福建 厦门 361021;2. 华侨大学 化工学院, 福建 厦门 361021
Author(s):
CHEN Xiaoyuan1;  JIN Chunying2;  LIN Jinqing1
1. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China; 2. College of Chemical Engineering, Huaqiao University, Xiamen 361021, China
关键词:
离子液体;  高级氧化技术;  废水处理;  氧化降解
Keywords:
ionic liquids(ILs);  advanced oxidation process(AOPs);  wastewater treatment;  oxidative degradation
分类号:
X703.1;O645.1
DOI:
10.11830/ISSN.1000-5013.202407036
文献标志码:
A
摘要:
离子液体(ionic liquids, ILs)是一类具有特殊性质的新兴材料,但其在水中的溶解度相对较高,容易通过废水排放进入水生系统并在环境中积累,且其结构非常稳定,难以被生物降解,具有潜在的生物毒性,因此被认为是一类持久污染物。高级氧化技术(advanced oxidation processes,AOPs)是一种高效降解难降解有机污染物的新技术,已被用于降解废水中的离子液体。文中综述芬顿和类芬顿氧化、阳极氧化、电芬顿氧化、光氧化、光催化氧化、光芬顿氧化及电光芬顿氧化等高级氧化技术降解处理废水中离子液体的研究进展;着重讨论各种氧化技术的降解动力学、降解机理、降解途径和优缺点,以及操作条件、离子液体的阴阳离子、侧链长度等因素对降解反应的影响规律,总结目前存在的问题,并对高级氧化技术降解处理离子液体的未来的研究方向及其前景进行了展望。
Abstract:
Ionic liquids(ILs)are a class of emerging materials with special properties, but their solubility in water is relatively high, making them easy to enter aquatic systems through wastewater discharge and accumulate in the environment. Their structure is very stable and difficult to biodegrade, making them a persistent pollutant with potential biological toxicity. Advanced oxidation processes(AOPs)is a new technology which can degrade recalcitrant organic pollutants efficiently and has been used to degrade ionic liquids in wastewater. This article reviews the research progress on the degradation and treatment of ILs in wastewater using various AOPs including Fenton and Fenton-like oxidation, anodic oxidation, electro-Fenton oxidation, photo-oxidation, photocatalytic oxidation, photo-Fenton oxidation, and photoelectro-Fenton oxidation. The review mainly focuses on discussing the degradation kinetics, mechanisms, pathways, advantages and disadvantages of these oxidation technologies. Additionally, the impact of operating conditions, anions and cations of ILs, and side chain length on degradation reactions are examined. The current challenges are summarized, and future research directions and prospects for AOPs in the degradation and treatment of ILs are proposed.

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[1]付宏权,刘培元,陈盈,等.离子液体［Bmim］PF6萃取处理硝基酚废水[J].华侨大学学报(自然科学版),2013,34(3):303.[doi:10.11830/ISSN.1000-5013.2013.03.0303]
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备注/Memo

备注/Memo:
收稿日期: 2024-07-10
通信作者: 林金清(1963-),男,教授,博士,博士生导师,主要从事离子液体的设计合成及其绿色催化、高级氧化技术处理新污染物的研究。E-mail:linlab@hqu.edu.cn。
基金项目: 国家自然科学基金资助项目(22278165, 21803021, 21246008); 福建省自然科学基金资助项目(2020J01065)https://hdxb.hqu.edu.cn/
更新日期/Last Update: 2024-07-20