[1]许景威,陈国华.石墨烯基气凝胶吸附材料在空气净化领域的研究进展[J].华侨大学学报(自然科学版),2023,44(6):661-670.[doi:10.11830/ISSN.1000-5013.202310007]
　XU Jingwei,CHEN Guohua.Research Progress of Graphene-Based Aerogel Adsorption Materials in Air Purification[J].Journal of Huaqiao University(Natural Science),2023,44(6):661-670.[doi:10.11830/ISSN.1000-5013.202310007]
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石墨烯基气凝胶吸附材料在空气净化领域的研究进展()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第44卷
期数:
2023年第6期
页码:
661-670
栏目:
出版日期:
2023-11-20

文章信息/Info

Title:
Research Progress of Graphene-Based Aerogel Adsorption Materials in Air Purification
文章编号:
1000-5013(2023)06-0661-10
作者:
许景威;  陈国华
华侨大学 材料科学与工程学院, 福建 厦门 362021
Author(s):
XU Jingwei;  CHEN Guohua
College of Material Science and Engineering, Huaqiao University, Xiamen 361021, China
关键词:
石墨烯气凝胶;  改性;  吸附机理;  空气净化
Keywords:
graphene aerogel;  modification;  adsorption mechanism;  air purification
分类号:
TQ427.26
DOI:
10.11830/ISSN.1000-5013.202310007
文献标志码:
A
摘要:
综述石墨烯气凝胶的制备方法及石墨烯基气凝胶作为吸附材料在空气净化领域中的应用现状,总结目前石墨烯气凝胶材料存在的问题,并对石墨烯气凝胶在空气净化吸附方面的未来发展方向提出展望。结果表明:石墨烯气凝胶是一种具有大比表面积、高孔隙率、多吸附位点的良好空气净化材料,经改性后的石墨烯气凝胶对气体污染物具有可观的化学吸附能力,结合自身物理吸附性能,成为了近年来备受关注的空气净化材料之一。
Abstract:
The preparation methods of graphene aerogel and application status of graphene-based aerogel as adsorption materials in the field of air purification are reviewed. The current existing problems of graphene aerogel materials are summarized and the future development direction of graphene aerogel in air purification adsorption is forecasted. The results show that the graphene aerogel is a good air purification material with large specific surface area, high porosity and multiple adsorption sites. The modified graphene aerogel has considerable chemical adsorption performance of gaseous pollutants. Combined with its own physical adsorption performance, it has become one of the most concerned air purification materials in recent years.

参考文献/References:

[1] ZHANG Xueyang,GAO Bin,CREAMER A E,et al.Adsorption of VOCs onto engineered carbon materials: A review[J].Journal of Hazardous Materials,2017,338(6):102-123.DOI:10.1016/j.jhazmat.2017.05.013.
[2] KIM J T,LEE C W,JUNG H J,et al.Application of 2D materials for adsorptive removal of air pollutants[J].ACS Nano,2022,16(11):17687-17707.DOI:10.1021/acsnano.2c07937.
[3] HUANG Yu,LU Yanfeng,NIU Ruiyuan,et al.Removal of indoor volatile organic compounds via photocatalytic oxidation: A short review and prospect[J].Molecules,2016,21(1):56-76.DOI:10.3390/molecules21010056.
[4] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.DOI:10.1126/science.1102896.
[5] ALIYEV E,FILIZ V,KHAN M M,et al.Structural characterization of graphene oxide: Surface functional groups and fractionated oxidative debris[J].Nanomaterials,2019,9(8):1180-1195.DOI:10.3390/nano9081180.
[6] 万文超.用于吸油和空气净化领域的石墨烯气凝胶材料的研究[D].成都:西南石油大学,2016.
[7] LIU Xiaoting,PANG Kai,YANG Hui,et al.Intrinsically microstructured graphene aerogel exhibiting excellent mechanical performance and super-high adsorption capacity[J].Carbon,2020,161(33):146-152.DOI:10.1016/j.carbon.2020.01.065.
[8] 龚焕焕,李德军,赵梦鲤.水热温度对3D石墨烯结构及蛋白吸附性能的调控[J].天津师范大学学报(自然科学版),2017,37(6):11-14,20.
[9] XU Xiang,ZHANG Qiangqiang,YU Yikang,et al.Naturally dried graphene aerogels with superelasticity and tunable poisson’s ratio[J].Advanced Materials,2016,28(41):9223-9230.DOI:10.1002/adma.201603079.
[10] RATHI K,KIM D.Super-compressible and mechanically stable reduced graphene oxide aerogel for wearable functional devices[J].Science and Technology of Advanced Materials,2023,24(1):1-11.DOI:10.1080/14686996.2023.2214854.
[11] NGUYET D M,QUAN T H,THINH D B,et al.Preparing three-dimensional graphene aerogels by chemical reducing method: Investigation of synthesis condition and optimization of adsorption capacity of organic dye[J].Surfaces and Interfaces,2021,23(8):101023-101036.DOI:10.1016/j.surfin.2021.101023.
[12] SAHINER N.Conductive polymer containing graphene aerogel composites as sensor for CO2[J].Polymer Composites,2018,40(s2):1208-1218.DOI:10.1002/pc.24947.
[13] JOKAR E,SHAHROKHIAN S,ASDIAN E,et al.An efficient two-step approach for improvement of graphene aerogel characteristics in preparation of supercapacitor electrodes[J].Journal of Energy Storage,2018,17(1):465-473.DOI:10.1016/j.est.2018.04.014.
[14] KUMAR R,ALAFERDOV A V,SINGH R K,et al.Self-assembled nanostructures of 3D hierarchical faceted-iron oxide containing vertical carbon nanotubes on reduced graphene oxide hybrids for enhanced electromagnetic interface shielding[J].Composites Part B-Engineering,2019,168(14):66-76.DOI:10.1016/j.compositesb.2018.12.047.
[15] LIU Sihang,XU Liangbo,YUAN Zhefan,et al.3D interlayer slidable multilayer nano-graphene oxide acrylate crosslinked tough hydrogel[J].Langmuir,2022,38(27):8200-8210.DOI:10.1021/acs.langmuir.2c00355.
[16] TONG Xin,JIA Wenjie,LI Youmei,et al.One-step preparation of reduced graphene oxide/Prussian blue/polypyrrole aerogel and their enhanced photo-fenton performance[J].Journal of the Taiwan Institute of Chemical Engineers,2019,102(33):92-98.DOI:10.1016/j.jtice.2019.05.008.
[17] BO Yuqin,YU Anran,LIU Huie,et al.Preparation of elastic graphene aerogel and its adsorption of oil[J].Journal of Porous Materials,2021,28(1):39-56.DOI:10.1007/s10934-020-00964-3.
[18] GARCIA-BORDEJE E,BENITO A M,MASER W K.Graphene aerogels via hydrothermal gelation of graphene oxide colloids: Fine-tuning of its porous and chemical properties and catalytic applications[J].Advances in Colloid and Interface Science,2021,292(27):1-18.DOI:10.1016/j.cis.2021.102420.
[19] HU Han,ZHAO Zongbin,WAN Wubo,et al.Ultralight and highly compressible graphene aerogels[J].Advanced Materials,2013,25(15):2219-2223.DOI:10.1002/adma.201204530.
[20] 李国臣,肖民,董其超,等.石墨烯基气凝胶的研究进展及应用综述[J].广州化工,2022,50(17):27-30.
[21] LI Chenwei,JIANG Degang,LIANG Hui,et al.Superelastic and arbitrary-shaped graphene aerogels with sacrificial skeleton of melamine foam for varied applications[J].Advanced Functional Materials,2018,28(8):1-9.DOI:10.1002/adfm.201704674.
[22] YANG Hongsheng,LI Zengling,SUN Guoqiang,et al.Superplastic air-dryable graphene hydrogels for wet-press assembly of ultrastrong superelastic aerogels with infinite macroscale[J].Advanced Functional Materials,2019,29(26):1-9.DOI:10.1002/adfm.201901917.
[23] WANG Chunhui,CHEN Xiong,WANG Bin,et al.Freeze-casting produces a graphene oxide aerogel with a radial and centrosymmetric structure[J].ACS Nano,2018,12(6):5816-5825.DOI:10.1021/acsnano.8b01747.
[24] YU Jingang,YU Linyan,YANG Hua,et al.Graphene nanosheets as novel adsorbents in adsorption, preconcentration and removal of gases, organic compounds and metal ions[J].Science of the Total Environment,2015,502(23):70-79.DOI:10.1016/j.scitotenv.2014.08.077.
[25] SURESH S,BANDOSZ T J.Removal of formaldehyde on carbon-based materials: A review of the recent approaches and findings[J].Carbon,2018,137(1):207-221.DOI:10.1016/j.carbon.2018.05.023.
[26] PEI Jingjing,ZHANG Jiangshun.On the performance and mechanisms of formaldehyde removal by chemi-sorbents[J].Chemical Engineering Journal,2011,167(1):59-66.DOI:10.1016/j.cej.2010.11.106.
[27] LI Hao,LI Tiehu,DENG Weibin,et al.Preparation and adsorption properties of graphene-modified, pitch-based carbon foam composites[J].Polymers,2022,14(20):4455-4467.DOI:10.3390/polym14204455.
[28] ZHOU Qingxiao,YUAN Lei,YANG Xi,et al.DFT study of formaldehyde adsorption on vacancy defected graphene doped with B, N, and S[J].Chemical Physics,2014,440(11):80-86.DOI:10.1016/j.chemphys.2014.06.016.
[29] JYOTI R,DEJI R,KAUR N,et al.A new insight into transition metal doped graphene nanoribbon for hydrogen sulfide gas adsorption: First principle investigation[J].Surfaces and Interfaces,2023,40(3):103154-103162.DOI:10.1016/j.surfin.2023.103154.
[30] LU Yunhua,XU Yanjie,ZHANG Junan,et al.Adsorption of carbon dioxide gas by modified graphene: A theoretical study[J].Chemistryselect,2022,7(7):1-12.DOI:10.1002/slct.202104067.
[31] TANG Shaobin,CAO Zexing.Adsorption of nitrogen oxides on graphene and graphene oxides: Insights from density functional calculations[J].Journal of Chemical Physics,2011,134(4):1-15.DOI:10.1063/1.3541249.
[32] LI Fen,JIANG Xue,ZHAO Jijun,et al.Graphene oxide:a promising nanomaterial for energy and environmental applications[J].Nano Energy,2015,16(8):488-515.DOI:10.1016/j.nanoen.2015.07.014.
[33] HE Yongqiang,ZHANG Nana,WU Fei,et al.Graphene oxide foams and their excellent adsorption ability for acetone gas[J].Materials Research Bulletin,2013,48(9):3553-3558.DOI:10.1016/j.materresbull.2013.05.056.
[34] PETIT C,SEREDYCH M,BANDOSZ T J.Revisiting the chemistry of graphite oxides and its effect on ammonia adsorption[J].Journal of Materials Chemistry,2009,19(48):9176-9185.DOI:10.1039/b916672f.
[35] FAN Chaojun,LI Sheng,LUO Mingkun,et al.Effects of N and S functionalities on binary gas co-adsorption on a coal macromolecule[J].Energy & Fuels,2019,33(5):3934-3946.DOI:10.1021/acs.energyfuels.8b04410.
[36] LIU Yamin,SAJJADI B,CHEN Weiyin,et al.Ultrasound-assisted amine functionalized graphene oxide for enhanced CO2 adsorption[J].Fuel,2019,247(33):10-18.DOI:10.1016/j.fuel.2019.03.011.
[37] HSAN N,DUTTA P K,KUMAR S,et al.Chitosan grafted graphene oxide aerogel: Synthesis, characterization and carbon dioxide capture study[J].International Journal of Biological Macromolecules,2019,125(21):300-306.DOI:10.1016/j.ijbiomac.2018.12.071.
[38] ALHWAIGE A A,AGAG T,ISHIDA H,et al.Biobased chitosan hybrid aerogels with superior adsorption: Role of graphene oxide in CO2 capture[J].RSC Advances,2013,3(36):16011-16020.DOI:10.1039/c3ra42022a.
[39] DU Wenjie,MA Rui,LIU Zhiyan,et al.Study on the adsorption properties of graphene oxide/laponite RD/chitosan composites[J].Materials,2021,14(12):1-13.DOI:10.3390/ma14123224.
[40] HUANG Huan,CHEN Pengwan,ZHANG Xuetong,et al.Edge-to-edge assembled graphene oxide aerogels with outstanding mechanical performance and superhigh chemical activity[J].Small,2013,9(8):1397-1404.DOI:10.1002/smll.201202965.
[41] LIANG Junfei,CAI Zhi,LI Lidong,et al. Scalable and facile preparation of graphene aerogel for air purification[J].RSC Advances,2014,4(10):4843-4847.DOI:10.1039/c3ra45147j.
[42] LIU Faqian,LI Wei,ZHAO Jie,et al.Covalent-grafting polyethyleneimine on hydroxylated three-dimensional graphene for superior CO2 capture[J].Journal of Materials Chemistry A,2015,3(23):12252-12258.DOI:10.1039/c5ta01536g.
[43] WU Jingjie,QIU Xianyu,CHEN Shuixia.Preparation and characterization of an amine-modified graphene aerogel for enhanced carbon dioxide adsorption[J].Chemical Routes to Materials,2022,57(3):1727-1737.DOI:10.1007/s10853-021-06768-3.
[44] OH Y,LE V D,MAITI U N,et al.Selective and regenerative carbon dioxide capture by highly polarizing porous carbon nitride[J].ACS Nano,2015,9(9):9148-9157.DOI:10.1021/acsnano.5b03400.
[45] 吴利瑞,张蓝心,于飞,等.氨基化碳纳米管/石墨烯气凝胶对甲醛吸附研究[J].中国环境科学,2015,35(11):3251-3256.
[46] MA Jie,SUN Yiran,YANG Jinhu,et al.High-performance amino-functional graphene/CNT aerogel adsorbent for formaldehyde removal from indoor air[J].Aerosol and Air Quality Research,2017,17(3):913-922.DOI:10.4209/aaqr.2016.07.0312.
[47] WU Lirui,QIN Ziyi,ZHANG Lanxin,et al.CNT-enhanced amino-functional graphene aerogel adsorbent for highly efficient removal of formaldehyde[J].New Journal of Chemistry,2017,41(7):2527-2533.DOI:10.1039/c6nj03643k.
[48] WANG Wuyou,ZHAO Xiaowen,YE Lin.Self-assembled construction of robust and super elastic graphene aerogel for high-efficient formaldehyde removal and multifunctional application[J].Small,2023,19(24):1-13.DOI:10.1002/smll.202300234.
[49] WU Lirui,ZHANG Lanxin,MENG Tao,et al.Facile synthesis of 3D amino-functional graphene-sponge composites decorated by graphene nanodots with enhanced removal of indoor formaldehyde[J].Aerosol and Air Quality Research,2015,15(3):1028-1034.DOI:10.4209/aaqr.2014.10.0237.
[50] WANG Wenjing,MOTUZAS J,ZHAO Xiusong,et al.2D/3D assemblies of amine-functionalized graphene silica(templated)aerogel for enhanced CO2 sorption[J].ACS Applied Materials & Interfaces,2019,11(33):30391-30400.DOI:10.1021/acsami.9b07192.
[51] VASSEGHIAN Y,LE V T,JOO S W,et al.Spotlighting graphene-based catalysts for the mitigation of environmentally hazardous pollutants to cleaner production: A review[J].Journal of Cleaner Production,2022,365(8):1-14.DOI:10.1016/j.jclepro.2022.132702.
[52] SUI Zhuyin,MENG Yuena,XIAO Peiwen,et al.Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents[J].ACS Applied Materials & Interfaces,2015,7(3):1431-1438.DOI:10.1021/am5042065.
[53] WU Jingjie,LIU Mingjie,SHARMA P P,et al.Incorporation of Nitrogen defects for efficient reduction of CO2 via two-electron pathway on three-dimensional graphene foam[J].Nano Letters,2016,16(1):466-470.DOI:10.1021/acs.nanolett.5b04123.
[54] PRUNA A,CARCEL A C,BENEDITO A,et al.Effect of synthesis conditions on CO2 capture of ethylenediamine-modified graphene aerogels[J].Applied Surface Science,2019,487(3):228-235.DOI:10.1016/j.apsusc.2019.05.098.
[55] PRUNA A,CARCEL A C,BENEDITO A,et al.The effect of solvothermal conditions on the properties of three-dimensional N-doped graphene aerogels[J].Nanomaterials,2019,9(3):1-13.DOI:10.3390/nano9030350.
[56] ANDROULIDAKIS C,KOTSIDI M,GORGOLIS G,et al.Multi-functional 2D hybrid aerogels for gas absorption applications[J].Scientific Reports,2021,11(1):13548-13560.DOI:10.1038/s41598-021-92957-8.
[57] SZCZESNIAK B,CHOMA J,JARONIEC M.Ultrahigh benzene adsorption capacity of graphene-MOF composite fabricated via MOF crystallization in 3D mesoporous graphene[J].Microporous and Mesoporous Materials,2019,279(11):387-394.DOI:10.1016/j.micromeso.2019.01.022.
[58] ZHANG Wenkun,HUANG Ting,REN Yu,et al.Preparation of chitosan crosslinked with metal-organic framework(MOF-199)@ aminated graphene oxide aerogel for the adsorption of formaldehyde gas and methyl orange[J].International Journal of Biological Macromolecules,2021,193(36):2243-2251.DOI:10.1016/j.ijbiomac.2021.11.056.
[59] 李厚志.石墨烯/ZIF-8复合气凝胶材料的制备及其性能研究[D].青岛:青岛科技大学,2017.
[60] LIU Kangkai,JIN Biao,MENG Longyue.Glucose/graphene-based aerogels for gas adsorption and electric double layer capacitors[J].Polymers,2019,11(1):1-16.DOI:10.3390/polym11010040.
[61] MALOLEPSZY A,MAZURKIEWICZ-PAWLICKA M,KOTKOWSKI T,et al.Synthesis of graphene foams and their sorption properties of n-hexane[J].Journal of Porous Materials,2021,28(4):1069-1079.DOI:10.1007/s10934-021-01054-8.

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[1]魏从容,魏永聪,吴季怀.新型橡胶补强剂的研究[J].华侨大学学报(自然科学版),1997,18(1):39.[doi:10.11830/ISSN.1000-5013.1997.01.0039]
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备注/Memo

备注/Memo:
收稿日期: 2023-10-07
通信作者: 陈国华(1964-),男,教授,博士,博士生导师,主要从事高分子材料、石墨烯材料制备与应用研究。E-mail:hdcgh@hqu.edu.cn。
基金项目: 国家自然科学基金资助项目(51373055); 福建省石墨烯粉体及复合材料工程技术研究中心资助项目(2017H2001); 福建省厦门市重点实验室资助项目(2023-01)
更新日期/Last Update: 2023-11-20