[1]曾宏,林少杰,方柏山.生物柴油酸催化甲醇法生产工艺全流程模拟与经济分析[J].华侨大学学报(自然科学版),2014,35(1):67-71.[doi:10.11830/ISSN.1000-5013.2014.01.0067]
 ZENG Hong,LIN Shao-jie,FANG Bai-shan.Process Simulation Analysis on Acid Catalysis Method for Biodiesel Production[J].Journal of Huaqiao University(Natural Science),2014,35(1):67-71.[doi:10.11830/ISSN.1000-5013.2014.01.0067]
点击复制

生物柴油酸催化甲醇法生产工艺全流程模拟与经济分析()
分享到:

《华侨大学学报(自然科学版)》[ISSN:1000-5013/CN:35-1079/N]

卷:
第35卷
期数:
2014年第1期
页码:
67-71
栏目:
出版日期:
2014-01-20

文章信息/Info

Title:
Process Simulation Analysis on Acid Catalysis Method for Biodiesel Production
文章编号:
1000-5013(2014)01-0067-05
作者:
曾宏12 林少杰2 方柏山34
1. 华侨大学 化工学院, 福建 厦门 361021;2. 泉州师范学院 化学与生命科学学院, 福建 泉州 362000;3. 厦门大学 化学化工学院, 福建 厦门 361005;4. 厦门大学 醇醚酯化工清洁生产国家工程实验室, 福建 厦门 361005
Author(s):
ZENG Hong12 LIN Shao-jie2 FANG Bai-shan34
1. College of Chemical Engineering, Huaqiao University, Xiamen 361021, China; 2. College of Chemistry and Life Sciences, Quanzhou Normal University, Quanzhou 362000, China; 3. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
关键词:
生物柴油 甘油三油酸酯 酸催化甲醇法 过程仿真 经济分析
Keywords:
biodiesel glycerol trioleate acid catalyzed methanol method process simulation economic analysis
分类号:
TQ018;TQ9
DOI:
10.11830/ISSN.1000-5013.2014.01.0067
文献标志码:
A
摘要:
应用SuperPro Designer流程模拟软件,对生物柴油酸催化甲醇法工艺进行全过程仿真模拟与计算,并技术经济分析.模拟结果表明:主要过程数据符合实验结果,生物柴油产品脂肪酸甲酯(FAME)质量分数大于97%,满足欧盟生物柴油标准,工艺流程设计合理.经济分析表明:年产8 000 t生物柴油的酸催化甲醇法工艺,其直接固定成本约2 078 万元,其中主要设备购置成本为363 万元,原料成本占操作成本71%以上;项目总投资约2 572 万元,税后净利润可达962 万元·a-1,投资收益
Abstract:
The Superpro Designer emluator was used to design and simulate the whole process of acid catalyzed methanol method technology for biodiesel production, by coupling with costing and economic evaluation of flowsheeting. Simulation results indicated that the process design was reasonable with main process data in agreement with experimental results. The mass fraction of fatty acid methyl ester(FAME)in biodiesel products was more than 97%, which met the EU biodiesel standards. The economic analysis showed that the direct fixed capital cost(DFC)was about 20.78 million CNY for acid catalyzed methanol technology of a 8 000 ton per year. The main equipment purchase cost was about 3.63 million CNY, and the cost of raw materials accounted for over 71% of the operating costs. The expected return on investment(ROI)was to reach 37.39% of approximately 25.72 million CNY project total investments, as the after-tax profits about 9.62 million CNY per year.

参考文献/References:

[1] 王永红,徐小红,刘泉山.国内外生物柴油的研究应用进展[J].润滑油与燃料,2003,13(1):20-24.
[2] FURUTA S,MATSUHASHI H,ARATA K.Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure[J].Catalysis Communications,2004,5(12):721-723.
[3] ABREU F R,AOVES M B,MACÊDO C C S,et al.New multi-phase catalytic system based on tin compounds active for vegetable oil transesterification reaction[J].Journal of Molecular Catalysis A: Chemical,2005,227(1/2):263-267.
[4] DISERIO M,TESSER R,DIMICCOLI M,et al.Synthesis of biodiesel via homogeneous Lewis acid catalyst[J].Journal of Molecular Catalysis A: Chemical,2005,239(1/2):111-115.
[5] JITPUTTI J,KITIYANAN B,RANGSUNVIGIT P,et al.Transesterification of crude palm kernel oil and crude coconut oil by different solid catalysts[J].Chemical Engineering Journal,2006,116(1):61-66.
[6] 姚亚光,纪威,符太军,等.酸催化地沟油与醇类酯化反应研究[J].粮食与油脂,2005,18(10):20-22.
[7] 张传龙,纪威,符太军,等.餐饮业废油脂生产生物柴油的实验研究[J].中国粮油学报,2005,20(6):94-97.
[8] 党亚固,费德君.均相法制备生物柴油的研究[J].现代化工,2009,29(增刊1):297-299.
[9] MYINT L L,El-Halwagi M M.Process analysis and optimization of biodiesel production from soybean oil[J].Clean Techn Environ Policy,2009,11(3):263-276.
[10] SANTANA G C S,MARTINS P F,de LIMA D S N,et al.Simulation and cost estimate for biodiesel production using castor oil[J].Chemical Engineering Research and Design,2010,88(5/6):626-632.
[11] 谢明霞.超临界法制备生物柴油的动力学研究与全流程模拟[D].天津:天津大学,2007:39-49.
[12] 单保明.大豆酸化油合成生物柴油的工艺研究[D].青岛:青岛科技大学,2008:46-63.
[13] 栾建美,郭善辉,蒋蕴珍.低酸一步法催化麻疯果油制备生物柴油[J].粮油食品科技,2009,17(1):13-16.
[14] 刘伟伟,马欢,张无敌,等.对甲苯磺酸催化高酸值油脂甲酯化的实验[J].中国油脂,2008,33(8):54-56.
[15] 钟鸣,张秀兰,李玉玲,等.磷酸催化地沟油制备生物柴油的研究[J].信阳师范学院学报:自然科学版,2008,21(4):570-572.
[16] 张勇.利用地沟油制备生物柴油[J].中国油脂,2008,33(11):48-50.
[17] 娄文勇,蔡俊,段章群,等.基于纤维素的固体酸催化剂的制备及其催化高酸值废油脂生产生物柴油[J].催化学报,2011,32(11):1755-1761.
[18] 李怀平,汪全义,兰先秋,等.离子液体[Hmim]HSO4催化菜籽油制备生物柴油[J].中国油脂,2008,33(4):57-59.
[19] BHATTI H N,HANIF M A,FARUQ U,et al.Acid and base catalyzed transesterification of animal fats to biodiesel[J].Iran J Chem Chem Eng,2008,27(4):41-48.
[20] JACOBSON K,GOPINATH R,MEHER L C,et al.Solid acid catalyzed biodiesel production from waste cooking oil[J].Applied Catalysis B: Environmental,2008,85(1/2):86-91.
[21] 曾宏,李洪明,方柏山.生物柴油超临界甲醇法生产工艺全流程模拟与经济分析[J].过程工程学报,2010,10(6):1168-1173.
[22] HAAS M J,MCALOON A J,YEE W C,et al.A process model to estimate biodiesel production costs[J].Bioresource Technology,2006,97(4):671-678.

相似文献/References:

[1]孙亚飞,林金清,左霜,等.功能化季铵盐离子液体在制备生物柴油中的应用[J].华侨大学学报(自然科学版),2011,32(6):657.[doi:10.11830/ISSN.1000-5013.2011.06.0657]
 SUN Ya-fei,LIN Jin-qing,ZUO Shuang,et al.Application of Synthesis Biodiesel by Functional Qauternary Ammonium Ionic Liquid[J].Journal of Huaqiao University(Natural Science),2011,32(1):657.[doi:10.11830/ISSN.1000-5013.2011.06.0657]
[2]李留,陈盈,林金清.三油酸甘油酯与甲醇反应合成生物柴油的热力学分析[J].华侨大学学报(自然科学版),2013,34(4):409.[doi:10.11830/ISSN.1000-5013.2013.04.0409]
 LI Liu,CHEN Ying,LIN Jin-qing.Thermodynamic Analysis of Triolein and Methanol Synthesis of Biodiesel[J].Journal of Huaqiao University(Natural Science),2013,34(1):409.[doi:10.11830/ISSN.1000-5013.2013.04.0409]
[3]赵强,林金清.磺酸基功能化季铵盐离子液体催化油酸制备生物柴油[J].华侨大学学报(自然科学版),2013,34(6):662.[doi:10.11830/ISSN.1000-5013.2013.06.0662]
 ZHAO Qiang,LIN Jin-qing.Preparation of Biodiesel from Oleic Acid by Using SO3H-Functionalized Quaternary Ammonium Ionic Liquids[J].Journal of Huaqiao University(Natural Science),2013,34(1):662.[doi:10.11830/ISSN.1000-5013.2013.06.0662]

备注/Memo

备注/Memo:
收稿日期: 2013-03-29
通信作者: 曾宏(1977-),男,副教授,博士,主要从事生物化工工艺的研究.E-mail:hongzeng@126.com.
基金项目: 福建省高校产学合作科技重大项目(2010H6023); 福建省教育厅A类科技项目(JA11219); 福建省泉州市技术研究与开发项目(2010G6)
更新日期/Last Update: 2014-01-20