[1]杜慷慨.苯甲酰丙酮缩水杨酰腙络镍铜配合物的合成与表征[J].华侨大学学报(自然科学版),2010,31(5):534-538.[doi:10.11830/ISSN.1000-5013.2010.05.0534]
　DU Kang-kai.Synthesis and Characterization of Complexes of Nickel and Copper by Benzoylacetone Salicylyl Hydrazone[J].Journal of Huaqiao University(Natural Science),2010,31(5):534-538.[doi:10.11830/ISSN.1000-5013.2010.05.0534]
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苯甲酰丙酮缩水杨酰腙络镍铜配合物的合成与表征()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第31卷
期数:
2010年第5期
页码:
534-538
栏目:
出版日期:
2010-09-20

文章信息/Info

Title:
Synthesis and Characterization of Complexes of Nickel and Copper by Benzoylacetone Salicylyl Hydrazone
文章编号:
1000-5013(2010)05-0534-05
作者:
杜慷慨
华侨大学材料科学与工程学院
Author(s):
DU Kang-kai
College of Material Science and Engineering, Huaqiao University, Quanzhou 362021, China
关键词:
配合物;  苯甲酰丙酮;  水杨酰腙;  铜;  镍
Keywords:
complex;  benzoylacetone;  salicylyl hydrazone;  copper;  nickel
分类号:
O627.12
DOI:
10.11830/ISSN.1000-5013.2010.05.0534
文献标志码:
A
摘要:
合成苯甲酰丙酮缩水杨酰腙配体,以及其镍配合物[Ni(C17H14N2O3)(C3N2H4)]和铜配合物[Cu(C17H14N2O3)(H2O)].X射线衍射仪研究表明,镍配合物属单斜晶系,a=1.719 7(7)nm,b=1.614 7(4)nm,c=1.503 9(4)nm,β=115.830(11)°,空间群是p21/c,Z=8; 而铜配合物属正交晶系,a=6.564 nm,b=10.158nm,c=24.031 nm,空间群属p212121,Z=4.最后,用荧光分析和热分析对两种配合物的性质进行表征.
Abstract:
Benzoylacetone salicylyl hydrazone was synthesized and used as a ligand to prepared nicklel and copper based complexes.The crystal structures of the complexes were determined by single-crystal X-ray diffraction.Nickel complex [Ni(C17H14N2O3)(C3N2H4)] belongs to monoclinic system,and its group is p2(1)/c,with the crystal cell parameters: a=1.719 7(7) nm,b=1.614 7(4) nm,c=1.503 9(4) nm,β=115.830(11)°,Z=8.Copper complex [Cu(C17H14N2O3)(H2O)] belongs to orthorhombic system,and its space group is p212121,with the crystal cell parameters: a= 6.564 nm,b=10.158 nm,c=24.031 nm,Z=4.The behavior of two complexes were further characterized with fluorometry and thermal analyzing.

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备注/Memo

备注/Memo:
国家自然科学基金资助项目(50673031); 福建省自然科学基金资助项目(2007J0223); 华侨大学科研基金资助项目(07BS509)
更新日期/Last Update: 2014-03-23