[1]黄海,徐旭波,黄庆添,等.碳纤维/MC尼龙6原位复合材料的非等温结晶动力学[J].华侨大学学报(自然科学版),2007,28(3):287-291.[doi:10.3969/j.issn.1000-5013.2007.03.017]
 HUANG Hai,XU Xu-bo,HUANG Qing-tian,et al.Non-Isothermal Crystallization Kinetics of CF/MC Nylon 6 In-Situ Composites[J].Journal of Huaqiao University(Natural Science),2007,28(3):287-291.[doi:10.3969/j.issn.1000-5013.2007.03.017]
点击复制

碳纤维/MC尼龙6原位复合材料的非等温结晶动力学()
分享到:

《华侨大学学报(自然科学版)》[ISSN:1000-5013/CN:35-1079/N]

卷:
第28卷
期数:
2007年第3期
页码:
287-291
栏目:
出版日期:
2007-07-20

文章信息/Info

Title:
Non-Isothermal Crystallization Kinetics of CF/MC Nylon 6 In-Situ Composites
文章编号:
1000-5013(2007)03-0287-05
作者:
黄海徐旭波黄庆添林金清林志勇
华侨大学材料科学与工程学院; 南安市环保局; 华侨大学材料科学与工程学院 福建泉州362021; 福建泉州362021; 福建泉州362300
Author(s):
HUANG Hai1 XU Xu-bo1 HUANG Qing-tian2 LIN Jin-qing1 LIN Zhi-yong1
1.College of Material Science and Engineering, Huaqiao University, Quanzhou 362021, China; 2.Office of Nanan Environmental Protection, Quanzhou 362300, China
关键词:
碳纤维 MC尼龙6 原位复合材料 非等温结晶 动力学
Keywords:
carbon fiber monomer casting nylon 6 in-situ composites non-isothermal crystallization kinetics
分类号:
TB332
DOI:
10.3969/j.issn.1000-5013.2007.03.017
文献标志码:
A
摘要:
采用差示扫描量热(DSC)法,研究表面接枝聚己内酰胺链段的碳纤维(CF)/单体浇铸(MC)尼龙6原位复合材料,以及其在不同冷却速率下的结晶动力学特性; 用Jeziorny法和Liu法对它们的非等温结晶动力学进行处理.结果表明,碳纤维对基体尼龙6的结晶有一定的促进作用,提高了结晶温度和结晶速率.表面接枝聚己内酰胺链段的碳纤维/MC尼龙6原位复合材料,比未接枝的碳纤维/MC尼龙6原位复合材料具有更高的结晶温度、结晶速率和更大的结晶度.
Abstract:
Non-isothermal crystallizations of the polycaprolactam chain segment grafted carbon fibre(CF)/monomer casting(MC) nylon 6 in-situ composites were investigated at different cooling rates by means of differential scanning calorimetry(DSC).Their non-isothermal crystallization kinetics were described by Jeziorny method and Liu method.Results showed that the carbon fiber can promote the crystallization of MC nylon 6 matrix and enhance crystallization temperatures and crystallization rates.The crystallization temperature,crystallization rate and crystallization degree of the polycaprolactam chain segment grafted CF/MC nylon 6 in-situ composites are higher than those of un-grafted CF/MC nylon 6.

参考文献/References:

[1] 任紫菊, 宁荣昌. 碳纤维增强MC尼龙的研究 [J]. 复合材料学报, 2000(2):16-19.doi:10.3321/j.issn:1000-3851.2000.02.004.
[2] BESSELL T, SHORTAL J B. The cystallization and interfacial bond strengh of nylon 6 at carbon and glass fiber surfaces [J]. 1975.2035-2043.
[3] 曲桂杰, 唐功本, 扬玉华. 浇铸尼龙6的结晶与熔融 [J]. 应用化学, 1995(2):76-79.
[4] CARTLEDGE H, BRILLIE C. Studies of microstructural and mechanical properties of nylonlglass composite:Tthe effect of thermal prolessing on crystallnity tramscry stallinity and crystal phases [J]. J Mator Sci, 1999, (20):5113-5126.doi:10.1023/A:1004765201803.
[5] YU Z, AITKIDA A, BRISSON J. Nylon/kevler composites(Ⅱ):Ivestigation of intertases [J]. Polymer Engineering and Science, 1991, (16):1228.
[6] ZHANG Z, KITANO T, HATAKEYAMA T. Crystallization behevior of carbon fiber reinforled pdyamides(Ⅰ):Dynamic and isothermal crystallization [J]. International Polymer Processing, 1995(2):165.
[7] 曾汉民. 树脂基复合材料界面工程 [A]. 北京:清华大学出版社, 1990.165-171.
[8] 贺福, 王茂章. 炭纤维及其复合材料 [M]. 北京:科学出版社, 1997.175-228.
[9] 林金清, 黄海, 徐旭波. 碳纤维/MC尼龙6原位复合材料的制备与表征 [J]. 华侨大学学报(自然科学版), 2006(1):92-95.doi:10.3969/j.issn.1000-5013.2006.01.025.
[10] BERNHARD W. Macromolecular physics [M]. New York:Academic Press, Inc, 1980.71.
[11] 刘结平, 莫志深. 聚合物结晶动力学 [J]. 高分子通报, 1991.199-207.
[12] HINRICHSEN G, LUX F. Crystallization kinetics of highly filled glass fiber/polyamide 6 composite [J]. Polymer Bulletin, 1990.79-86.doi:10.1007/BF00298325.

相似文献/References:

[1]杜慷慨,林志勇.碳纤维表面氧化的研究[J].华侨大学学报(自然科学版),1999,20(2):136.[doi:10.11830/ISSN.1000-5013.1999.02.0136]
 Du Kangkai,Lin Zhiyong.Oxidation on the Surface of Carbon Fibers[J].Journal of Huaqiao University(Natural Science),1999,20(3):136.[doi:10.11830/ISSN.1000-5013.1999.02.0136]
[2]林志勇,杜慷慨,叶葳.碳纤维表面氧化还原研究[J].华侨大学学报(自然科学版),1999,20(4):354.[doi:10.11830/ISSN.1000-5013.1999.04.0354]
 Li Zhiyong,Du Kangkai,Ye Wei.Oxidation and Reduction on the surface of Carbon Fiber[J].Journal of Huaqiao University(Natural Science),1999,20(3):354.[doi:10.11830/ISSN.1000-5013.1999.04.0354]
[3]姚辉梅,黄锦河,林志勇.高含量CF/PA6复合材料的非等温结晶动力学[J].华侨大学学报(自然科学版),2007,28(2):159.[doi:10.3969/j.issn.1000-5013.2007.02.013]
 YAO Hui-mei,HUANG Jin-he,LIN Zhi-yong.Studies on Nonisothermal Crystallization of High Content Carbon Fiber Reinforced Nylon 6 Composites[J].Journal of Huaqiao University(Natural Science),2007,28(3):159.[doi:10.3969/j.issn.1000-5013.2007.02.013]

备注/Memo

备注/Memo:
福建省自然科学基金资助项目(E0210022)
更新日期/Last Update: 2014-03-23