[1]王森林.玻璃上Ag/ZnO薄膜的形成过程[J].华侨大学学报(自然科学版),2004,25(3):263-265.[doi:10.3969/j.issn.1000-5013.2004.03.010]
　Wang Senlin.Forming Process of Ag/ZnO Film on Glass[J].Journal of Huaqiao University(Natural Science),2004,25(3):263-265.[doi:10.3969/j.issn.1000-5013.2004.03.010]
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玻璃上Ag/ZnO薄膜的形成过程()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第25卷
期数:
2004年第3期
页码:
263-265
栏目:
出版日期:
2004-07-20

文章信息/Info

Title:
Forming Process of Ag/ZnO Film on Glass
文章编号:
1000-5013(2004)03-0263-03
作者:
王森林
华侨大学材料科学与工程学院 福建泉州362021
Author(s):
Wang Senlin
College of Mater. Sci. & Eng., Huaqiao Univ., 362021, Quanzhou, China
关键词:
氧化锌薄膜;  玻璃;  银;  光化学还原
Keywords:
zinc oxide film;  glass;  silver;  photochemical reduction
分类号:
TQ153
DOI:
10.3969/j.issn.1000-5013.2004.03.010
文献标志码:
A
摘要:
扩展一种和玻璃基体结合力高的化学镀铜技术,它在玻璃表面上喷雾覆盖一层醋酸锌,然后热解形成半导体氧化锌薄膜 .将此附有氧化锌的玻璃浸渍硝酸银稀溶液,利用光还原法将银离子还原为单质银,并以银为催化剂在附有氧化锌薄膜的玻璃上化学镀铜 .文中通过差热 热重分析 (TG DTA)、X 射线衍射 (XRD)和扫描电境 (SEM)表征了上述过程,探讨半导体氧化锌光还原银离子的机理 .
Abstract:
A technique of electroless plating was developed for preparing a copper layer with strong adhesion to glass substrate. A layer of zinc acetate was sprayed on the surface of glass, and then a zinc oxide film as a semiconductor was formed by pyrolysis. Dipping this zinc oxide adsorbed glass into dilute solution of silver nitrate, silver ion was reduced into silver as simple substance by photo reduction. The silver was used as catalyst in electroless plating of copper on the zinc oxide film adsorbed glass. In this paper, the processes mentioned above was characterized by differential thermal analysis thermogravimetry, X ray diffraction, and scanning electron microscope; and the mechanism of photo reduction of silver ion by zinc oxide semiconductor was discussed.

参考文献/References:

[1] Yoshiki H, Kitahara H, Hashimoto K. Pattern formation of Cu layer by photocatalytic reaction of ZnO thin film [J]. Journal of the Electrochemical Society, 1995, (12):235-237.doi:10.1149/1.2048510.
[2] Yoshiki H, Alexandruk V, Hashimoto K. Electroless copper plating using ZnO thin film coated on a glass substrate [J]. Journal of the Electrochemical Society, 1994(5):56-58.doi:10.1149/1.2054935.
[3] 王森林, 刘明光, 卢雪蓉. 覆盖有ZnO薄膜的玻璃基体上化学镀铜 [J]. 材料保护, 2000, (10):9-10.doi:10.3969/j.issn.1001-1560.2000.10.004.
[4] 王森林. TiO2/SiO2的制备及光催化性能 [J]. 华侨大学学报(自然科学版), 2002(2):129-132.doi:10.3969/j.issn.1000-5013.2002.02.004.

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备注/Memo

备注/Memo:
福建省自然科学基金资助项目(E0210020)
更新日期/Last Update: 2014-03-23