[1]汪光武,何　镛,阮福生.相转移催化合成α-三氯代甲基苄原醇乙酸酯[J].华侨大学学报(自然科学版),1994,15(2):168-171.[doi:10.11830/ISSN.1000-5013.1994.02.0168]
　Wang Guangwu,He Yingyong,Ruan Fusheng.Synthesis of α-(Trichloro Methyl)Benzyl Acetate by Phase Transfer Catalysis[J].Journal of Huaqiao University(Natural Science),1994,15(2):168-171.[doi:10.11830/ISSN.1000-5013.1994.02.0168]
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相转移催化合成α-三氯代甲基苄原醇乙酸酯()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第15卷
期数:
1994年第2期
页码:
168-171
栏目:
出版日期:
1994-04-20

文章信息/Info

Title:
Synthesis of α-(Trichloro Methyl)Benzyl Acetate by Phase Transfer Catalysis
作者:
汪光武; 何　镛; 阮福生
华侨大学应用化学系; 厦门食品厂
Author(s):
Wang Guangwu;  He Yingyong;  Ruan Fusheng
关键词:
相转移催化;  合成;  α-三氯代甲基苄原醇;  α-三氯代甲基苄原醇乙酸酯
Keywords:
phase transfer catalysis;  synthesis;  α-(Trichloro methyl) benzyl alcohol;  α-(Trichloro methyl) benzyl acetate
分类号:
O623.426
DOI:
10.11830/ISSN.1000-5013.1994.02.0168
摘要:
阐述在合成α-三氯代甲基苄原醇乙酸酯及其主要原料α-三氯代甲基苄原醇中,采用相转移催化的基本原理和方法.考察反应时间、原料配比和催化剂用量对α-三氯代甲基苄原醇乙酸酯的影响.在反应时间为5h,原料α-三氯代甲基苄原醇和乙酸酐的摩尔配比为1:1.2,无水醋酸钠催化剂和相转移催化剂(PTC4#)为α-三氯代甲基苄原醇摩尔数10%时,其α-三氯代甲基苄原醇乙酸酯产率为76%~80%.
Abstract:
In synthesizing α-(Trichloro methyl)benzyl acetate and the main material-α(Trichloro methyl)benzyl alcohol,the basic principle and method of phase transfer catalysis were described.The influences of reaction time, mix ratio of raw materials,and the amount

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备注/Memo

备注/Memo:
福建省自然科学基金
更新日期/Last Update: 2014-03-22