[1]乐其河,江开勇.活性添加剂分散调控对镀铜线精细化的影响[J].华侨大学学报(自然科学版),2025,46(4):379-385.[doi:10.11830/ISSN.1000-5013.202504038]
 LE Qihe,JIANG Kaiyong.Influence of Dispersion Control of Active Additives on Refinement of Copper Plated Wire[J].Journal of Huaqiao University(Natural Science),2025,46(4):379-385.[doi:10.11830/ISSN.1000-5013.202504038]
点击复制

活性添加剂分散调控对镀铜线精细化的影响()
分享到:

《华侨大学学报(自然科学版)》[ISSN:1000-5013/CN:35-1079/N]

卷:
第46卷
期数:
2025年第4期
页码:
379-385
栏目:
出版日期:
2025-07-16

文章信息/Info

Title:
Influence of Dispersion Control of Active Additives on Refinement of Copper Plated Wire
文章编号:
1000-5013(2025)04-0379-07
作者:
乐其河 江开勇
华侨大学 福建省特种能场制造重点实验室, 福建 厦门 361021
Author(s):
LE Qihe JIANG Kaiyong
Fujian Key Laboratory of Special Energy Manufacturing, Huaqiao University, Xiamen 361021, China
关键词:
电解加工 激光活化 化学镀铜 线条精细化 颗粒分散性
Keywords:
electrochemical machining laser activation electroless plating copper refinement particle dispersibility
分类号:
TQ153.14
DOI:
10.11830/ISSN.1000-5013.202504038
文献标志码:
A
摘要:
针对柔性阴极电解加工中镀铜线条边缘精细化问题,研究添加剂颗粒粒度及分散性对镀铜质量的影响。调整添加剂颗粒的研磨时间与浆料搅拌方式,并结合激光活化及化学镀铜工艺,制备导电线路并分析其形貌。结果表明:添加剂颗粒的研磨时间对其粒度有显著影响,经48 h研磨的颗粒粒度稳定在1.445 μm,分散性提升,团聚减少;采用高速分散机搅拌5 min后聚氨酯中的颗粒面积分数较传统搅拌降低了11.9%;添加剂颗粒细化与均匀分散改善了激光活化催化中心的均匀性,当研磨时间达48 h、搅拌时间为5 min时,镀铜线条边缘整齐清晰,线条分布均匀,线宽约为85.1 μm。
Abstract:
To address the issue of edge refinement of copper plated wires in flexible cathode electrochemical machining, the influence of additive particle size and dispersion on copper plating quality was studied. The grinding time of additive particles and the slurry stirring method were adjusted, and laser activation was combined with electroless copper plating processes to prepare conductive wires and their morphology was analyzed. The results demonstrated that grinding time significantly influenced the particle size, which stabilized at 1.445 μm after 48 hours of grinding, with improved dispersibility and reduced agglomeration. After stirring for 5 minutes using a high-speed disperser, the particle area fraction in polyurethane decreased by 11.9% compared to traditional stirring. The refinement and uniformly dispersed additive particles improved the uniformity of laser activated catalytic centers. Under the optimal conditions(48 hours grinding and 5 minutes high-speed stirring), the copper plated wires exhibited sharp and well-defined edges, uniform distribution, and a consistent wire width of approximately 85.1 μm.

参考文献/References:

[1] 佚名.LPKF在中国天津建立激光直接成型三维模塑互连器件应用中心[J].印制电路信息,2008(9):38.
[2] 刘新民.MID工艺制程塑模电子互联部件图案金属化工艺[C]//第十届全国转化膜及表面精饰学术年会论文集.南宁:中国表面工程协会转化膜专业委员会,2014:144-148.
[3] 刘述梅,陈红,赵建青,等.热致液晶高分子膜的表面处理及化学镀铜[J].塑料工业,2024,52(2):60-65.DOI:10.3969/i.issn.1005-5770.2024.02.009.
[4] PAN Chengfeng,KUMAR K,LI Jianzhao,et al.Visually imperceptible liquid-metal circuits for transparent, stretchable electronics with direct laser writing[J].Advanced Materials,2018,30:1706937.DOI:10.1002/adma.201706937.
[5] 代竟雄.基于激光诱导的3D电子线路成型工艺研究[D].绵阳:西南科技大学,2018.
[6] 叶玉梅,江开勇,张际亮.改性塑料表面亚铜化合物的表征及催化化学镀铜作用[J].材料科学与工艺,2014,22(5):124-128.DOI:10.11951/j.issn.1005-0299.20140522.
[7] 平玉清,江开勇.脉冲激光改性聚氨酯表面无钯化学镀铜的实验研究[J].工程塑料应用,2015,43(3):54-59.DOI:10.3969/i.issn.1001-3539.2015.03.011.
[8] MATSUHISA N,CHEN Xiaodong,BAO Zhenan,et al.Materials and structural designs of stretchable conductors[J].Chemical Society Reviews,2019,48:2946-2966.DOI:10.1039/C8CS00814K.
[9] 王攀,崔开放,钟良.聚酰亚胺塑料表面激光诱导活化化学镀铜[J].电镀与环保,2020,40(3):30-33.DOI:10.3969/j.issn.1000-4742.2020.03.009.
[10] XU Haoran,FENG Jin,YU Feifan,et al.Laser-induced selective metallization on polymers for both NIR and UV lasers: Preparing 2D and 3D circuits[J].Industrial & Engineering Chemistry Research,2023,62(1):395-404.DOI:10.1021/acs.iecr.2c03367.
[11] LU Yinxiang.Improvement of copper plating adhesion on silane modified PET film by ultrasonic-assisted electroless deposition[J].Applied Surface Science,2010,256(11):3554-3558.DOI:10.1016/j.apsusc.2009.12.153.
[12] SON J,HONG Y,YAVUZ C T,et al.Thiourea-based extraction and deposition of gold for electroless nickel immersion gold process[J].Industrial & Engineering Chemistry Research,2020,59(16):8086-8092.DOI:10.1021/acs.iecr.0c00493.
[13] JONES T D A,RYSPAYEVA A,ESFAHANI M N,et al.Direct metallisation of polyetherimide substrates by activation with different metals[J].Surface & Coatings Technology,2019,360:285-296.DOI:10.1016/j.surfcoat.2019.01.023.
[14] GU Xin,WANG Zhoucheng,LIN Changjian.An electrochemical study of the effects of chelating agents and additives on electroless copper plating[J].Journal of Electrochemistry,2004,11(1):49-55.DOI:10.61558/2993-074X.1539.
[15] 续振林,郭琦龙,沈艺程,等.陶瓷表面无敏化活化法微细化学镀铜[J].电化学,2005,11(2):193-198.DOI:10.13208/j.electrochem.2005.02.016.
[16] 宋轩.电解加工表面织构用柔性阴极制备及其加工实验研究[D].厦门:华侨大学,2020.
[17] 王广阔,杨英贤.不同超声频率与温度对纳米ZnO颗粒分散性能的影响[J].纺织科技进展,2005(2):3.DOI:10.3969/j.issn.1673-0356.2005.02.009.
[18] 何飞,黄振亚,刘靖,等.复合材料内高含量固体的分散性评价方法[J].火炸药学报,2013,36(6):4.DOI:10.3969/j.issn.1007-7812.2013.06.016.

备注/Memo

备注/Memo:
收稿日期: 2025-04-22
通信作者: 乐其河(1991-),男,实验师,主要从事特种加工的研究。E-mail:leqihe@hqu.edu.cn。
基金项目: 国家自然科学基金资助项目(51475174)
更新日期/Last Update: 2025-07-20