[1]王文栋,王轶楠,饶海彬,等.纳米结构石墨相氮化碳用于CO2催化转化的研究进展[J].华侨大学学报(自然科学版),2024,45(5):575-587.[doi:10.11830/ISSN.1000-5013.202407028]
　WANG Wendong,WANG Yinan,RAO Haibin,et al.Progress of Nanostructured Graphitic Carbon Nitride for CO2 Catalytic Conversion[J].Journal of Huaqiao University(Natural Science),2024,45(5):575-587.[doi:10.11830/ISSN.1000-5013.202407028]
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纳米结构石墨相氮化碳用于CO2催化转化的研究进展()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第45卷
期数:
2024年第5期
页码:
575-587
栏目:
出版日期:
2024-09-20

文章信息/Info

Title:
Progress of Nanostructured Graphitic Carbon Nitride for CO2 Catalytic Conversion
文章编号:
1000-5013(2024)05-0575-13
作者:
王文栋;  王轶楠;  饶海彬;  郭芳松;  詹国武
华侨大学 先进碳转化技术研究院, 福建 厦门 362021
Author(s):
WANG Wendong;  WANG Yinan;  RAO Haibin;  GUO Fangsong;  ZHAN Guowu
Academy of Advanced Carbon Conversion Technology, Huaqiao University, Xiamen 361021, China
关键词:
石墨相氮化碳(g-C3N4);  二氧化碳还原反应(CO2RR);  催化性能;  光催化;  电催化;  纳米结构
Keywords:
graphitic carbon nitride(g-C3N4);  carbon dioxide reduction reaction(CO2RR);  catalytic performance;  photocatalysis;  electrocatalysis;  nanostructure
分类号:
TB34;O643.36
DOI:
10.11830/ISSN.1000-5013.202407028
文献标志码:
A
摘要:
系统性地梳理了石墨相氮化碳(g-C3N4)在光/电催化二氧化碳还原反应(CO2RR)的最新研究进展,深入探讨了通过精细调控其局域电子结构、表面化学配位、电荷传输机制及光学特性等关键参数所实现的催化性能提升。具体策略涵盖了结构优化设计、缺陷工程引入、元素/分子掺杂策略以及异质结构构建等前沿技术,这些创新方法为g-C3N4催化剂的定制化设计提供了丰富的工具箱。最后,对面临的挑战和前景进行了简要的总结和展望,以期为进一步合理设计g-C3N4作为选择性高效的CO2RR催化剂。
Abstract:
This paper comprehensively reviews the state-of-the-art advancements in graphitic carbon nitride(g-C3N4)for electrocatalytic and photocatalytic carbon dioxide reduction reaction(CO2RR). The improvement of catalytic performance by fine-tuning the key parameters of their local electronic structures, surface chemical coordination, charge transport mechanisms, and optical properties was discussed in detail. Highlighted approaches encompass cutting-edge methodologies like structural optimization, defect engineering, elemental/molecular doping and heterostructure assembly, collectively offering a versatile arsenal for tailored design of g-C3N4 catalysts. The review culminates in a concise synopsis of existing challenges and future perspectives, aiming to guide the rational development of g-C3N4 as highly selective and efficient CO2RR catalysts.

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备注/Memo

备注/Memo:
收稿日期: 2024-07-16
通信作者: 郭芳松(1989-),男,副研究员,博士,主要从事集成催化剂材料等方面的研究。E-mail:fsguo@hqu.edu.cn。
基金项目: 国家自然科学基金资助项目(U21A20324, 22278167, 22322806); 华侨大学科研启动项目(22BS138)
更新日期/Last Update: 2024-09-20