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ISSN.1000-5013.202109013]
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Cu基材料电催化二氧化碳深度还原研究进展()

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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:: 第43卷
期数:: 2022年第1期

页码:: 1-13

栏目:

出版日期:: 2022-01-09

文章信息/Info

Title:: Research Progress of Copper-Based Materials for Electrocatalytic CO₂ Deep Reduction

文章编号:: 1000-5013(2022)01-0001-13

作者:: 谢水奋¹; 孔伟强¹; 王秋祥²; 1. 华侨大学材料科学与工程学院, 福建厦门 361021;2. 华侨大学实验室与设备管理处, 福建厦门 361021

Author(s):: XIE Shuifen¹; KONG Weiqiang¹; WANG Qiuxiang²; 1. College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China; 2. Laboratory and Equipment Management Department, Huaqiao University, Xiamen 361021, China

关键词:: 二氧化碳还原; 串联催化; Cu基催化剂; 深度还原产物

Keywords:: CO₂ reduction; tandem catalysis; Cu-based catalysts; deep reduction products

分类号:: O646

DOI:: 10.11830/ISSN.1000-5013.202109013

文献标志码:: A

摘要:: 综述近年来Cu基材料电催化CO₂还原(ECR)生成多碳产物的研究进展,着重介绍ECR反应机理、Cu基催化材料的各种设计策略及电解池系统优化,并展望未来该领域的发展方向.结果表明:Cu基催化剂的优化和设计能够有效降低^*CO关键中间体产生及偶联的能垒,进而优化多碳产物的合成效率;原位检测技术时空分辨率的提升则有助于深入ECR认识反应机理,从而优化Cu基材料的设计合成.

Abstract:: The research progress of Cu-based materials for electrocatalytic CO₂ reduction(ECR)to generate polycarbonate products is reviewed, with emphasis on the reaction mechanism of ECR, various design strategies of Cu-based catalytic materials and electrolytic cell system optimization, and the future development direction of this field. The results show that the optimization and design of Cu-based catalysts can effectively reduce the energy barriers for the production and coupling of key intermediates of ^*CO, and thus optimize the synthesis efficiency of polycarbonate products; the improvement of spatial and temporal resolution of in situ detection technology can help to deeply understand the reaction mechanism of ECR, and thus optimize the design and synthesis of Cu-based materials.

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备注/Memo

备注/Memo:: 收稿日期: 2021-09-10
通信作者: 谢水奋(1984-),男,教授,博士,主要从事无机纳米材料在燃料电池、电解水制氢、CO₂还原及环境治理等领域基础应用的研究.E-mail:sfxie@hqu.edu.cn.
基金项目: 国家自然科学基金资助项目(21771067, 22171093); 福建省自然科学基金资助项目(2017J06005); 福建省高校新世纪优秀人才支持计划(2018年度)

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