[1]张艺,龚安达,李华杰,等.6-氨乙胺基-6-脱氧壳聚糖对卷烟烟气中苯酚的吸附性能[J].华侨大学学报(自然科学版),2020,41(1):72-76.[doi:10.11830/ISSN.1000-5013.201905019]
　ZHANG Yi,GONG Anda,LI Huajie,et al.Adsorption Property of Phenol in Cigarette Smoke by 6-Aminoethylamine-6-Deoxychitosan[J].Journal of Huaqiao University(Natural Science),2020,41(1):72-76.[doi:10.11830/ISSN.1000-5013.201905019]
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6-氨乙胺基-6-脱氧壳聚糖对卷烟烟气中苯酚的吸附性能()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第41卷
期数:
2020年第1期
页码:
72-76
栏目:
出版日期:
2020-01-20

文章信息/Info

Title:
Adsorption Property of Phenol in Cigarette Smoke by 6-Aminoethylamine-6-Deoxychitosan
文章编号:
1000-5013(2020)01-0072-05
作者:
张艺1;  龚安达2;  李华杰2;  李明春1;  辛梅华1
1. 华侨大学 材料科学与工程学院, 福建 厦门 361021;2. 福建中烟工业有限责任公司 技术中心, 福建 厦门 361021
Author(s):
ZHANG Yi1;  GONG Anda2;  LI Huajie2;  LI Mingchun1;  XIN Meihua1
1. College of Material Science and Engineering, Huaqiao University, Xiamen 361021, China; 2. Technology Center, China Tobacco Fujian Industrial Limited Company, Xiamen 361021, China
关键词:
壳聚糖;  改性;  苯酚;  卷烟主流烟气;  吸附性能
Keywords:
chitosan;  chemical modification;  phenol;  mainstream cigarette smoke;  adsorption performance
分类号:
TS411.2
DOI:
10.11830/ISSN.1000-5013.201905019
文献标志码:
A
摘要:
以壳聚糖(CS)、氯化亚砜和乙二胺为原料,制备6-氨乙胺基-6-脱氧壳聚糖(ACS).产物采用傅里叶变换红外光谱,氢谱核磁和元素分析等方法进行表征.研究ACS在溶液中对苯酚的吸附性能,以及对卷烟主流烟气中有害成分的吸附情况.结果表明:在pH值为5.0,吸附时间为2 h的条件下,ACS对苯酚的吸附量随着苯酚质量浓度的增大而增加,其对苯酚的饱和吸附量为140.85 mg·g-1;ACS作为添加剂应用到卷烟滤嘴中,可不同程度地减少主流烟气中的7种有害成分,对烟气中的苯酚具有选择性吸附效果;常规滤嘴、含CS和ACS滤嘴的卷烟危害指数分别为8.04,7.41和6.78.
Abstract:
6-Aminoethylamine-6-deoxychitosan(ACS)was prepared from chitosan(CS), sulfoxide chloride and ethylenediamine. The product was characterized by Fourier transform infrared, nuclear magnetic resonance and elemental analysis. The adsorption of ACS on phenol in solution was studied, and then ACS was used on the adsorption of harmful components in mainstream cigarette smoke. The results showed that the adsorption capacity of ACS on phenol was increased with the increase of phenol mass concentration under the condition of pH 5.0 and adsorption time 2 h, and the saturated adsorption capacity of ACS on phenol was 140.85 mg·g-1. ACS could reduce the seven harmful components in the mainstream cigarette smoke in different degrees when used as an additive in cigarette filters, and it had selective adsorption effect on phenol. The cigarette hazard index of the conventional filters, filters with CS and ACS were 8.04, 7.41 and 6.78, respectively.

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备注/Memo

备注/Memo:
收稿日期: 2019-05-12
通信作者: 辛梅华(1962-),女,教授,博士,博士生导师,主要从事功能高分子材料的研究.E-mail:mhxin@hqu.edu.cn.
基金项目: 福建省海洋高新产业发展专项项目(闽海洋高新［2015］22号)
更新日期/Last Update: 2020-01-20