[1]张彬,宋磊.活性炭材料的孔径结构对SO2吸附性能的影响[J].华侨大学学报(自然科学版),2014,35(3):293-298.[doi:10.11830/ISSN.1000-5013.2014.03.0293]
 ZHANG Bin,SONG Lei.Effect of Pore Structure of Activated Carbon on Adsorption Properties of SO2[J].Journal of Huaqiao University(Natural Science),2014,35(3):293-298.[doi:10.11830/ISSN.1000-5013.2014.03.0293]
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活性炭材料的孔径结构对SO2吸附性能的影响()
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《华侨大学学报(自然科学版)》[ISSN:1000-5013/CN:35-1079/N]

卷:
第35卷
期数:
2014年第3期
页码:
293-298
栏目:
出版日期:
2014-05-16

文章信息/Info

Title:
Effect of Pore Structure of Activated Carbon on Adsorption Properties of SO2
文章编号:
1000-5013(2014)03-0293-06
作者:
张彬 宋磊
华侨大学 化工学院, 福建 厦门 361021
Author(s):
ZHANG Bin SONG Lei
College of Chemical Engineering, Huaqiao University, Xiamen 361021, China
关键词:
活性炭 孔径结构 SO2吸附 吸附动力学
Keywords:
activated carbon pore structure SO2 adsorption adsorption kinetic
分类号:
X511
DOI:
10.11830/ISSN.1000-5013.2014.03.0293
文献标志码:
A
摘要:
为了研究在常温下活性炭材料孔径结构及材料形态对SO2吸附性能的影响,以5种不同孔径结构的沥青基活性炭纤维及活性炭颗粒为材料,通过吸附动力学模型的拟合,考查了活性炭孔径结构及材料形态与SO2吸附速率的关系.结果表明:较小的微孔径结构更有利于SO2的吸附;不同孔径结构的活性炭材料对SO2的吸附均符合Bangham动力学过程,活性炭纤维的吸附速率随孔径的增大而增大;活性炭颗粒因其形态结构的差异,吸附速度较活性炭纤维慢,吸附效
Abstract:
Five pitch-based activated carbon fibers with different pore structure and activated carbon particles were used for SO2 adsorption at room temperature. The effects of activated carbon pore structure and material morphology were investigated, and their impacts on the rate of adsorption were studied by adsorption kinetics as well. The results showed that, the smaller micropore structure is more conducive to its adsorption. The SO2 adsorption process of the activated carbon material can be described by Bangham kinetic equation, and the adsorption rate of activated carbon fibers increases with specific surface area and pore size. The adsorption rates of GAC are slower than ACF, and the SO2 adsorption properties of GAC are worse than ACF due to the different morphology.

参考文献/References:

[1] 张守玉,向银花,赵建涛,等.活性炭质材料脱硫机理探讨[J].煤炭转化,2002,25(2):29-34.
[2] BAGREEV A,BASHKOVA S,BANDOSZ T J.Adsorption of SO2 on activated carbons: The effect of nitrogen functionality and pore sizes[J].Langmuir,2002,18(4):1257-1264.
[3] MANGUN C L,DEBARR J A,ECONOMY J.Adsorption of sulfur dioxide on ammonia-treated activated carbon fibers[J].Carbon,2001,39(11):1689-1696.
[4] CENTENO T A,MARBÁN G,FUERTES A B.Importance of micropore size distribution on adsorption at low adsorbate concentrations[J] Carbon,2003,41(4):843-846.
[5] LU Q,SORIAL G A.The role of adsorbent pore size distribution in multicomponent adsorption on activated carbon[J].Carbon,2004,42(15):3133-3142.
[6] PELEKANI C,SNOEYINK V L.A kinetic and equilibrium study of competitive adsorption between atrazine and Congo red dye on activated carbon the importance of pore size distribution[J].Carbon,2001,39(1):25-37.
[7] ZHU Yu-wen,GAO Ji-hui,LI Yang,et al.Preparation of activated carbons for SO2 adsorption by CO2 and steam activation[J].Journal of the Taiwan Institute of Chemical Engineers,2012,43(1):112-119.
[8] 高德霖,孙小玉.活性炭纤维和微孔吸附的容积充填理论[J].精细化工原料及中间体,2003(10):2-6.
[9] 蒋文举,江霞,朱晓帆,等.微波处理对活性炭孔隙结构的影响[J].林产化学与工业,2004,24(1):21-24.
[10] 方平,岑超平,唐志雄,等.污泥含炭吸附剂对甲苯的吸附性能研究[J].高校化学工程学报,2010,24(5):887-892.
[11] RAYMUNDO-PINERO E,de LECEA C,LINARES-SOLANO A,et al.Factors controling the SO2 removal by porous carbons relevance of the SO2 oxidation step[J].Carbon,2000,38(3):335-344.
[12] KANEKO K,ISHII C.Superhigh surface area determination of microporous solids[J].Colloids Surf,1992,67:203-212.
[13] SONG L,JUN-ICHI M,HIROFUMI K,et al.Enhancement of the methylene blue adsorption rate for ultramicroporous carbon fiber by addition of mesopores[J].Carbon,2006,44(10):1884-1890.
[14] 田莹莹,刘恩辉,沈海杰,等.茶籽壳质活性炭的制备及其化学性能[J].功能材料,2012,43(6):752-755.
[15] ATANES E, NIETO-MáRQUEZ A,CAMBRA A,et al.Adsorption of SO2 onto waste cork powder-derived activated carbons[J].Chemical Engineering Journal,2012,211/212(15):60-67.
[16] MOCHIDA I,KORAI Y,SHIRAHAMA M,et al.Removal of SOx and NOx over activated carbon fibers[J].Carbon,2000,38(2):227-239.
[17] 高继贤,王铁峰,王光润,等.不同烟气水蒸气体积分数时ZL50活性炭吸附SO2的动力学[J].清华大学学报:自然科学版,2010,50(3):434-437.
[18] AKSU Z.Biosorption of reactive dyes by dried activated sludge: Equilibrium and kinetic modeling[J].Biochemical EngineeringJournal,2001,7(1):79-84
[19] HO Y S,MCKAY G.The kinetics of sorption of divalent metal ions onto sphagnum moss peat[J].Water Research,2000,34(3):735-742.
[20] THINALARAM N,PANNEERSELVAM P,BASKARALINGAM P,et al.Equilibrium and kinetic studies on the removal of Acid Red 114 from aqueous solutions using activated carbons prepared from seed shells[J].J Hazard Mater,2008,158(1):142-150.
[21] WANG Li,CAO Bin,WANG Shu-dong,et al.H2S catalytic oxidation on impregnated activated carbon: Experiment and modeling[J].Chemical Engineering Journal,2006,118(3):133-139.
[22] 高继贤,王铁峰,王金福.SO2体积分数对 ZL50 活性炭吸附脱硫行为的影响和动力学分析[J].环境科学,2010,31(5):1152-1159.

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备注/Memo

备注/Memo:
收稿日期: 2013-05-14
通信作者: 宋磊(1973-),男,副教授,主要从事环境材料的研究.E-mail:songlei@hqu.edu.cn.
基金项目: 中央高校基本科研业务费专项资助项目, 华侨大学基本科研业务费专项基金资助(JB-ZR1150); 中央高校基本科研业务费专项资助项目, 华侨大学高层次人才科研启动项目(11BS215)
更新日期/Last Update: 2014-05-20