[1]郑燕玉,胡炳环,林金火.漆酚基乳化剂对O/W型生漆乳液性能的影响[J].华侨大学学报(自然科学版),2009,30(2):171-174.[doi:10.11830/ISSN.1000-5013.2009.02.0171]
　ZHENG Yan-yu,HU Bing-huan,LIN Jin-huo.The Effect of Urushiol-Based Emulsifier on the Properties of O/W Raw Lacquer Emulsion[J].Journal of Huaqiao University(Natural Science),2009,30(2):171-174.[doi:10.11830/ISSN.1000-5013.2009.02.0171]
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漆酚基乳化剂对O/W型生漆乳液性能的影响()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第30卷
期数:
2009年第2期
页码:
171-174
栏目:
出版日期:
2009-03-20

文章信息/Info

Title:
The Effect of Urushiol-Based Emulsifier on the Properties of O/W Raw Lacquer Emulsion
文章编号:
1000-5013(2009)02-0171-04
作者:
郑燕玉; 胡炳环; 林金火
泉州师范学院化学与生物学院; 福建师范大学化学与材料学院
Author(s):
ZHENG Yan-yu1;  HU Bing-huan2;  LIN Jin-huo2
1.Institute of Chemistry and Biology, Quanzhou Normal College, Quanzhou 362000, China; 2.College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
关键词:
O/W型生漆乳液;  漆酚基乳化剂;  聚乙烯醇;  稳定性;  流变性
Keywords:
O/W raw lacquer emulsion;  urushiol-based emulsifier;  stability;  rheological behavior;  mixed emulsifier UE/PVA
分类号:
TQ630.1
DOI:
10.11830/ISSN.1000-5013.2009.02.0171
文献标志码:
A
摘要:
以漆酚基乳化剂(UE)和聚乙烯醇(PVA)为混合乳化剂,制备稳定的水包油(O/W)型生漆乳液(RLE),研究UE的结构对RLE的稳定性、粒子形态及其流变性的影响.实验结果表明,由UE8D/PVA及UE10B/PVA混合乳化剂制备的RLE贮存稳定性好,RLE在常温下可贮存90 d以上不分层; 除了UE8A外,用不同UE制备的RLE粒子均为球形,其直径小于400 nm; RLE都有剪切变稀的特性,表现出假塑性流体的行为; 随着UE分子中聚氧乙烯链的增长,RLE的粘度增大,RLE粒子间所形成的某种静态空间网状结构强度增强.
Abstract:
The oil/water(O/W) type raw lacquer emulsion(RLE) was prepared using urushiol-based emulsifier(UE)/polyvinyl alcohol(PVA) mixture as the emulsifier.The effect of UE structure on RLF stability,diameter of RLE particles and rheology of RLE were investigated.The results shows that RLE prepared using emulsifier of UE8D/PVA and UE10B/PVA shows higher stability for storage,and it can be stored at ambient temperature for more than 3 months without creaming.The RLE particle is of sphere with a diameter less than 400 nm.RLE was belonged to pseudoplastic fluids and shear-thinning character was observed.The viscosity of RLE increased with increasing of the chain length of oxyethyl groups in UE molecules.Networklike structure between RLE particles goes stronger with increasing of chain length of oxyethyl groups in UE molecules.

参考文献/References:

[1] 甘景镐, 甘纯玑, 胡炳环. 天然高分子化学 [M]. 北京:高等教育出版社, 1993.138-141.
[2] 李艳菊, 王性炎. 中国生漆漆液研究 [J]. 林产化学与工业, 1997(2):41-46.
[3] 何天白, 胡汉杰. 功能高分子与新技术 [M]. 北京:化学工业出版社, 2001.192-205.
[4] 郑燕玉, 胡炳环, 林金火. 用混合乳剂UE20/PVA制备的水包油型生漆乳液的性能 [J]. 高等学校化学学报, 2008(7):1466-1472.doi:10.3321/j.issn:0251-0790.2008.07.037.
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备注/Memo

备注/Memo:
国家自然科学基金资助项目(50473063); 教育部博士点科研基金资助项目(20050394001); 泉州市科技计划重点项目(2005G3)
更新日期/Last Update: 2014-03-23