[1]刘玮炜,李娜,唐丽娟,等.2,3-双芳亚氨基-1,4-二硫杂环己烷EIMS谱特征[J].华侨大学学报(自然科学版),2007,28(4):390-393.[doi:10.3969/j.issn.1000-5013.2007.04.015]
　LIU Wei-wei,LI Na,TANG Li-juan,et al.The Spectroscopy Characteristics of EIMS of 2,3-Biarylimino-1,4-Dithiacyclohexane[J].Journal of Huaqiao University(Natural Science),2007,28(4):390-393.[doi:10.3969/j.issn.1000-5013.2007.04.015]
点击复制

2,3-双芳亚氨基-1,4-二硫杂环己烷EIMS谱特征()
分享到：

《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第28卷
期数:
2007年第4期
页码:
390-393
栏目:
出版日期:
2007-10-20

文章信息/Info

Title:
The Spectroscopy Characteristics of EIMS of 2,3-Biarylimino-1,4-Dithiacyclohexane
文章编号:
1000-5013(2007)04-0390-04
作者:
刘玮炜; 李娜; 唐丽娟; 赵跃强; 胡宏纹
淮海工学院化学工程系; 南京大学化学系 江苏连云港222005; 江苏连云港222005; 江苏南京210093
Author(s):
LIU Wei-wei1;  LI Na1;  TANG Li-juan1;  ZHAO Yue-qiang1;  HU Hong-wen2
1.Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China; 2.Department of Chemistry, Nanjing University, Nanjing 210093, China
关键词:
硫烷基化;  2; 3-双芳基亚氨基-1; 4-二硫杂环己烷;  电子轰击质谱;  裂解
Keywords:
S-alkylation;  2; 3-biarylimino-1; 4-dithiacyclohexane;  EIMS;  fragmentation
分类号:
TQ450
DOI:
10.3969/j.issn.1000-5013.2007.04.015
文献标志码:
A
摘要:
利用硫原子上的烷基化反应,合成出5个2,3-双芳基亚氨基-1,4-二硫杂环己烷类化合物,由元素分析、红外光谱分析(IR)1、H核磁共振谱分析(1H NMR)、质谱分析(MS)初步确定化合物的结构,并以单晶X射线衍射分析对其结构进一步确证.研究这5个化合物的电子轰击质谱(EIMS),探讨并归纳其裂解规律,总结该类化合物的EIMS谱特征.
Abstract:
Five compounds of 2,3-biarylimino-1,4-dithiacyclohexane were prepared by S-alkylation,the structure of them were analyzed by elemental analysis,IR(infrared),1H NMR(nuclear magnetic resonance) and MS(mass spectrometry) preliminarily,and further confirmed by X-ray diffraction.The 1H NMR,EIMS(electron impact mass spectrometry) specta of 2,3-biarylimino-1,4-dithiacyclohexane were studied in detail.The possible fragmentation mechanism for these compounds was proposed,and the EIMS characteristics of the title compounds have been summarized systematically.

参考文献/References:

[1] FERRARIS J P, COWAN D O, WALATKA V. Electron transfer in a new highly conducting donor-acceptor complex [J]. Journal of the American Chemical Society, 1973.948-949.
[2] BENHAMOU Y. Treatment algorithm for chronic hepatitis B in HIV-infected patients [J]. Journal of Hepatology, 2006(1):90-94.
[3] 朱再明, 梅泽民, 王寅. α-氧代烯酮环二硫代缩酮化学 [J]. 合成化学, 2000(2):164-166.doi:10.3969/j.issn.1005-1511.2000.02.016.
[4] 苟绍华, 陈洪超, 方治平. 2-取代亚肼基-1, 3-二硫杂环戊烷类化合物的合成及其生物活性研究 [J]. 有机化学, 2004(2):234-238.doi:10.3321/j.issn:0253-2786.2004.02.019.
[5] 何明, 张成琬. 新杀菌剂叶枯灵防治水稻白叶枯病研究 [J]. 植物保护学报, 1990(1):83-87.
[6] JORGENSEN K A. Catalytic asymmetric hetero-diels-alder reactions of carbonyl compounds and imines [J]. Angewandte Chemie International Edition, 2000.3558-3588.

相似文献/References:

[1]刘嘉川,程琳.2,3,6,7-四甲基三蝶烯的新型有效合成及表征[J].华侨大学学报(自然科学版),2012,33(5):518.[doi:10.11830/ISSN.1000-5013.2012.05.0518]
　LIU Jia-chuan,CHENG Lin.New Efficient Synthesis and Characterization of 2,3,6,7-Tetramethyltriptycene[J].Journal of Huaqiao University(Natural Science),2012,33(4):518.[doi:10.11830/ISSN.1000-5013.2012.05.0518]

备注/Memo

备注/Memo:
国家自然科学基金资助项目(20072016); 江苏省教育厅自然科学基金资助项目(03KJB150009); 淮海工学院学科建设基金资助项目(XK01009)
更新日期/Last Update: 2014-03-23