[1]王森林,陈志明.Fe-Ni-P合金电沉积机理[J].华侨大学学报(自然科学版),2007,28(3):275-277.[doi:10.3969/j.issn.1000-5013.2007.03.014]
　WANG Sen-lin,CHEN Zhi-ming.Mechanism of Electro-Deposition of Fe-Ni-P Alloy[J].Journal of Huaqiao University(Natural Science),2007,28(3):275-277.[doi:10.3969/j.issn.1000-5013.2007.03.014]
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Fe-Ni-P合金电沉积机理()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第28卷
期数:
2007年第3期
页码:
275-277
栏目:
出版日期:
2007-07-20

文章信息/Info

Title:
Mechanism of Electro-Deposition of Fe-Ni-P Alloy
文章编号:
1000-5013(2007)03-0275-03
作者:
王森林; 陈志明
华侨大学材料工程与工程学院; 华侨大学材料工程与工程学院 福建泉州362021; 福建泉州362021
Author(s):
WANG Sen-lin;  CHEN Zhi-ming
College of Materials Science and Engineering, Huaqiao University, Quanzhou 362021, China
关键词:
Fe-Ni-P合金;  电沉积;  成核机理;  沉积行为
Keywords:
Fe-Ni-P alloy;  electro-deposition;  mechanism of nucleation;  behavior of deposition
分类号:
TQ153.1
DOI:
10.3969/j.issn.1000-5013.2007.03.014
文献标志码:
A
摘要:
采用阴极极化技术和循环伏安技术,研究Fe-Ni-P合金的电化学特性.实验结果表明,Fe-Ni-P合金较Fe-Ni合金有较负的沉积电位,随着镀液pH值的增加,Fe-Ni-P合金的阴极沉积反应速度变小.采用恒电位阶跃技术研究Fe-Ni-P合金的电结晶行为,结果表明,在玻碳电极上,该合金的电结晶过程遵循瞬时成核三维生长模式,且随着过电位的增加,电极表面晶核数增多.
Abstract:
The electrochemical properties of Fe-Ni-P alloy were measured by cathodic polarization and cyclic voltammetry.The results show that the plating potential of Fe-Ni-P alloy is more negative than that of Ni-Fe alloy.The electro-crystallization of Fe-Ni-P alloy on vitreous carbon with methods of I~t transient curve was studied.It′s indicated that the electro-crystallization of Fe-Ni-P alloy follows the mechanism of instantaneous nucleation and three dimensional growth,and with the increase of plating potential the number of crystal nucleus increases.

参考文献/References:

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[2] SRIDHARAN K, SHEPPARD K. The electrodeposition of amorphous iron-nickel-phosphorus alloy coating [J]. Transactions of the Institute of Metal Finishing, 1994(4):153-158.
[3] SRIDHARAN K, SHEPPARD K. Electrochemical characterization of Fe-Ni-P alloy electrodeposition [J]. Journal of Applied Electrochemistry, 1997.1198-1206.doi:10.1023/A:1018475718629.
[4] GAO Cheng-hui, ZHOU Bai-yang. The structure and properties of different composition of Ni-Fe-P deposit [J]. Transactions of Nonferrous Metals Society of China, 1996(3):81-85.
[5] WANG Sen-ling, WU Hui-huang. The electroless plating Ni-Fe-P alloy and its voltammetric behavior [J]. Electrochemistry, 2003(3):327-335.doi:10.3969/j.issn.1006-3471.2003.03.012.
[6] SCHARIFLKER B, HILLS G. Theoretical and experimental studies of multiple nucleation [J]. Electrochimica Acta, 1983(7):879-889.doi:10.1016/0013-4686(83)85163-9.

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备注/Memo

备注/Memo:
福建省自然科学基金资助项目(E0210020)
更新日期/Last Update: 2014-03-23