[1]钱浩,林志勇,张莹雪.大分子表面改性剂的设计合成研究进展[J].华侨大学学报(自然科学版),2006,27(4):337-342.[doi:10.3969/j.issn.1000-5013.2006.04.001]
　Qian Hao,Lin Zhiyong,Zhang Yingxue.Review on the Synthesis Techniques for the Surface Modifying Macromolecules[J].Journal of Huaqiao University(Natural Science),2006,27(4):337-342.[doi:10.3969/j.issn.1000-5013.2006.04.001]
点击复制

大分子表面改性剂的设计合成研究进展()
分享到：

《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第27卷
期数:
2006年第4期
页码:
337-342
栏目:
出版日期:
2006-10-20

文章信息/Info

Title:
Review on the Synthesis Techniques for the Surface Modifying Macromolecules
文章编号:
1000-5013(2006)04-0337-06
作者:
钱浩; 林志勇; 张莹雪
华侨大学材料科学与工程学院; 华侨大学材料科学与工程学院 福建泉州362021; 福建泉州362021
Author(s):
Qian Hao;  Lin Zhiyong;  Zhang Yingxue
College of Material Science and Engineering, Huaqiao University, 362021, Quanzhou, China
关键词:
大分子表面改性剂;  设计合成;  聚合物材料;  表面改性;  表面迁移
Keywords:
surface modifying macromolecules;  synthesis;  polymer;  surface modification;  surface selective migration
分类号:
TQ423
DOI:
10.3969/j.issn.1000-5013.2006.04.001
文献标志码:
A
摘要:
简述大分子表面改性剂的发展过程和基本分类,提出大分子表面改性剂设计合成的基本原则,即化学结构和使用环境相匹配、憎水基功能团和亲水基功能团相适应、使用效率和功能持久性相平衡.文中介绍了大分子表面改性剂合成的主要方法、基本结构和改性的基本原理,以及影响其迁移扩散的主要因素.
Abstract:
The development and the essential assortment of the surface modifying macromolecules(SMM) were general summarized and the fundamental principles about the design and synthesis of the surface modifying macromolecules were discussed.First,the chemical structure of the SMM must be suitable to the applying environment.Second,the selected hydrophilic groups on the SMM should be fitted to the hydrophobic groups.Last,both the applying efficiency and the effective performance life of the SMM should be put into attention during the synthesis of the corresponding SMM.The prime methods,structures,mechanisms about the synthesis of the SMM and also the factors that could affect its selective migration were also introduced.

参考文献/References:

[1] Chan Chiming. Polymer surface modification and characterization [M]. New York:Hanser/Gardner Publications, 1994.8-26.
[2] Daniel E S, Geeta C, Takeshi M. Study on the rinetics of surface migration of surface modifying macromolecules in membrane preparation [J]. Macromolecules, 2002, (8):3017-3021.doi:10.1021/ma011205a.
[3] Keisha B W, Dwight W S, Douglas E H. Surface characterization of linear low-density polyethylene films modified with fluorinated additives [J]. Langmuir, 2003, (14):5851-5860.doi:10.1021/la026293m.
[4] Thomas H R, O’Malley J J. Surface studies on multicomponent polymer systems by X-ray photoelectron spectroscopy:Polystyrene/poly(ethylene oxide) homopolymer blends [J]. Macromolecules, 1981.1316.
[5] Strauss U P. Polymers in aqueous media:Performance through association [J]. Journal of Polymer Science, 1951(5):473.
[6] Strauss U P. Viscosity of sodium salt of polyuronide hemicellulose from Jute [J]. Journal of Polymer Science, 1952(6):509.doi:10.1002/pol.1952.120090604.
[7] 化工部科技情报研究所. 世界精细化工手册 [M]. 北京:化学工业出版社, 1985.209.
[8] 赵国玺. 表面活性剂物理化学 [M]. 北京:北京大学出版社, 1991.158.
[9] 陈永春, 易昌风, 程时远. 高分子表面活性剂的研究现状 [J]. 日用化学工业, 1997(5):25.
[10] Patric J. Surface structure and dynamics of block and graft copolymer having fluorinated poly(ethylene oxide) chain ends [J]. Macromolecules, 1998, (4):1341.doi:10.1021/ma971351+.
[11] 矶田孝一, 藤本武彦. 表面活性剂 [M]. 北京:中国轻工业出版社, 1973.328.
[12] 徐坚. 高分子表面活性剂的分子设计 [J]. 高分子通报, 1997(6):90.
[13] Lasckewsky A. Polymerizable and polymeric zwitterionic surfactants (Ⅰ):Synthesis and bulk properties [J]. POLYMER, 1991(1):2070.doi:10.1016/0032-3861(91)90175-I.
[14] Schmiddt J J, Gardella J A, Salvati L J. Surface studies of polymer blends (Ⅱ):An ESCA, IR and DSC study of poly(ε-caprolactone)/poly(vinyl chloride) homopolymer blends [J]. Macromolecules, 1989.4489.doi:10.1021/ma00202a019.
[15] Landoll L M. Nonionic polymer surfactants [J]. Journal of Polymer Science Part A:Polymer Chemistry, 1982.443.
[16] Lee H, Lynden A A. Functionalizing polymer surfaces by surface migration of copolymer additives:Role of additive molecular weight [J]. POLYMER, 2002, (9):2721.doi:10.1016/S0032-3861(02)00041-1.
[17] 范悦, 嵇培军, 徐坚. 聚乙烯醇高分子表面活性剂的研究 [J]. 化工冶金, 1997(3):217.
[18] 吴培熙, 张留城. 聚合物共混改性 [M]. 北京:中国轻工业出版社, 1996.322.
[19] Xie X M, Chen Y, Zheng Z M. Controls of gradient morphology and surface properties of polymer blends [J]. Macromolecules, 1999.4424.
[20] Niranjan M P, David W D. Surface and bulk separation in block copolymers and their blends polysulfone/polysiloxane [J]. MACROMOLECULES, 1988.2689.doi:10.1021/ma00187a007.
[21] Lee H, Lynden A A. Functionalizing polymer surfaces by fieled-induced migration of copolymer additives (Ⅰ):Role of surface energy gradients [J]. Macromolecules, 2001, (13):4572.doi:10.1021/ma001278e.
[22] Tao G L, Gong A, David E B. Surface functionalized polypropylene:Synthesis, characterization, and adhesion properties [J]. Macromolecules, 2001, (22):7672.doi:10.1021/ma010941b.
[23] Ruth L M, Sonja K, Wu P. Surface characterization of ethylene-vinyl (EVA) and ethylene-acrylic acid (EAA) copolymers using XPS and AFM [J]. POLYMER, 1998, (21):5223.doi:10.1016/S0032-3861(97)10177-X.
[24] 钱浩. 添加型大分子表面改性剂的设计合成及其对聚乙烯表面极性的改性研究 [D]. 广州:中山大学, 2002.94.

备注/Memo

备注/Memo:
福建省自然科学基金资助项目(E0510019); 福建省科技创新基金资助项目(2003J023)
更新日期/Last Update: 2014-03-23