[1]洪掌珠,林碧洲.链状十五聚钒酸盐的水热合成和晶体结构[J].华侨大学学报(自然科学版),2001,22(4):412-417.[doi:10.3969/j.issn.1000-5013.2001.04.018]
　Hong Zhangzhu,Lin Bizhou.Hydrothermal Synthesis and Crystal Structure of Chain-Like Pentadecovanadate[J].Journal of Huaqiao University(Natural Science),2001,22(4):412-417.[doi:10.3969/j.issn.1000-5013.2001.04.018]
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链状十五聚钒酸盐的水热合成和晶体结构()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第22卷
期数:
2001年第4期
页码:
412-417
栏目:
出版日期:
2001-10-20

文章信息/Info

Title:
Hydrothermal Synthesis and Crystal Structure of Chain-Like Pentadecovanadate
文章编号:
1000-5013(2001)04-0412-06
作者:
洪掌珠; 林碧洲
华侨大学材料科学与工程学院; 华侨大学材料科学与工程学院 泉州362011; 泉州362011
Author(s):
Hong Zhangzhu;  Lin Bizhou
College of Mater. Sci. & Eng., Huaqiao Univ., 362011, Quanzhou
关键词:
多聚钒酸盐;  晶体结构;  水热合成
Keywords:
polyoxovanadate;  crystal structure;  hydrothermal synthesis
分类号:
O743.51; O76
DOI:
10.3969/j.issn.1000-5013.2001.04.018
文献标志码:
A
摘要:
在 V2 O5:Cu Cl2 :1,2 - pn:H2 O物质的量之比为 3:1:8:4 0 0、反应温度为 15 0℃、反应时间为 3d的水热条件下,获得黑色针状 [Cu(1,2 - pn) 2 (H2 O) ]2 { [Cu(1,2 - pn) 2 ][V15O36 (Cl) ]} .H2 O晶体 .X-射线单晶结构分析表明,该晶体属正交晶系、Cmcm空间群,a=1.2 676(3) nm,b=2 .0 931(4 )nm,c=2 .2 5 77(5 ) nm.在晶体结构中,笼形 [V15O36 (Cl) ]6 -钒氧簇与 [Cu(1,2 - pn) 2 ]2 +配位基团通过 Cu- O的共价配位作用连接成一维阴离子链,阳离子配位基团 [Cu(1,2 - pn) 2 (H2 O) ]2 +占据链间位置,起着电荷平衡的空间补偿作用 .
Abstract:
Black needle-shaped crystals [Cu(1,2-pn) 2(H 2O)] 2{[Cu(1,2-pn) 2][V 15 O 36 (Cl)]}·H 2O were obtained by hydrothermal reaction of V 2O 5, CuCl 2, 1,2-diamino propane and H 2O in molar ratio of 3∶1∶8∶400 at 150 ℃ for three days. As determined by X-ray structural analysis of single crystal, this compound is crystallized in rhomic system, Cmcm space group with a=1.2 676(3) nm, b=2.0 931(4) nm, c=2.2 577(5) nm. In the crystal structure, the cage-like clusters [V 15 O 36 (Cl)] 6- connect with the coordination groups [Cu(1,2-pn) 2] 2+ throgh Cu-O covalent interactions and form an one-dimensional anion chains, while the cation groups [Cu(1,2-pn) 2(H 2O)] 2+ occupy the interchain position and take the roles of charge balance and space compensations.

参考文献/References:

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[6] Yamase T, Ohtaka K. Photochemistry of polyoxovanadates: Formation of the anionencapsulated polyoxovanadate [V15O36(CO3)]5- [J]. Journal of the Chemical Society Dalton Transactions, 1994, (19):2599-2608.doi:10.1039/dt9940002599.
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备注/Memo

备注/Memo:
福建省自然科学基金资助项目
更新日期/Last Update: 2014-03-23