[1]吴文士,张锡祺,董美斌,等.CdI2与TSC加成物的合成及结构[J].华侨大学学报(自然科学版),1998,19(2):147-150.[doi:10.11830/ISSN.1000-5013.1998.02.0147]
　Wu Wenshi,Zhang Xiqi,Dong Meibing,et al.Synthesis and Structure of the Addition Product of Cadmium Iodide and Thiosemicarbazide[J].Journal of Huaqiao University(Natural Science),1998,19(2):147-150.[doi:10.11830/ISSN.1000-5013.1998.02.0147]
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CdI2与TSC加成物的合成及结构()
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《华侨大学学报（自然科学版）》[ISSN:1000-5013/CN:35-1079/N]

卷:
第19卷
期数:
1998年第2期
页码:
147-150
栏目:
出版日期:
1998-04-20

文章信息/Info

Title:
Synthesis and Structure of the Addition Product of Cadmium Iodide and Thiosemicarbazide
作者:
吴文士; 张锡祺; 董美斌; 刘世雄
华侨大学应用化学系; 福州大学化学系
Author(s):
Wu Wenshi;  Zhang Xiqi;  Dong Meibing;  Li Shixiong
关键词:
碘化镉;  硫代氨基脲;  加成物;  晶体结构
Keywords:
cadmium iodide;  thiosemicarbazide;  complex;  crystal structure
分类号:
O743.53
DOI:
10.11830/ISSN.1000-5013.1998.02.0147
摘要:
CdI2与TSC在丙酮溶剂及水中形成加成物CdI2(C4H10N3S)2·H2O,晶体属单斜晶系,空间群为P21/m.晶胞参数为a=0.7533(3)nm,b=1.535(2)nm,c=0.8437(2)nm,β=90.91(3)°,v=0.976(1)nm3,Mr=648.64,Z=2,Dc=2.20g·cm-3,μ(CuKα)=44.58cm-1,F(000)=608,T=297K.用1622个I≥3σ(I)独立衍射精修结构,最终偏差因子R=0.057,晶体中存在分离的单核络合物CdI2(C4H10N
Abstract:
An addition product Cd 2(C 4H 10 N 3S) 2·H 2O is synthesized from cadmium iodide and thiosemicarbazide (TSC) in the solvent of acetone and water. Its crystal belongs to monoclinic system, with a space group of P2 1/m. The cell parameters include: a =0.753

备注/Memo

备注/Memo:
福建省自然科学基金
更新日期/Last Update: 2014-03-22